生物气残留的直接价值化:对简单的化学修饰进行比较研究,以提高阳离子染料的吸附性
Xin Luo1, Wenxia Zhao2, Lin Fu1,3
1Key Laboratory of Original Agro-Environmental Pollution Prevention and Control, Tianjin Key Laboratory of Agro-Environment and Agro-Product Safety, Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs (MARA), Tianjin 300191, China.
Toxics
|January 28, 2026
概括
生物气残留物 (BR) 的酸 (HCl) 改性产生了一种具有成本效益的吸附剂,用于去除像刚果红 (CR) 这样的离子染料. 与氨基酸离子液体 (AAIL) 或氧化 (NaOH) 相比,这种方法提供了更好的性能和可重复使用性.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 废弃物价值化 废弃物价值化 废弃物价值化
背景情况:
- 富含素的生物气残留物 (BR) 是一个未充分利用的废物流.
- 开发有效的吸附剂来去除离子染料对于废水处理至关重要.
- 传统的BR改造方法在性能和环境影响方面存在局限性.
研究的目的:
- 为了比较基于HCl,NaOH和L-氨酸的氨基酸离子液体 (AAILs),用于修改BR.
- 开发一个具有成本效益和可扩展的战略,用于将BR提升为高性能吸附剂.
- 调查离子染料去除的吸附机制和再生效率.
主要方法:
- 使用HCl,NaOH和AAILs对非碳化BR进行修改.
- 使用刚果红色 (CR) 作为离子染料的吸附实验.
- 使用诸如BET表面积分析和零电荷点 (pHPZC) 确定等技术对吸附剂进行表征.
- 吸附异温和运动模型 (Langmuir,伪二阶).
主要成果:
- 化物修饰 (BR-HCl) 通过"选择性溶解-孔隙重建"机制产生了最高的CR吸附能力 (120.21毫克/克在45°C).
- 由于更高的同电点 (pHPZC ≈ 9.02),BR-HCl表现出增强的静电吸引力,使其能够在广泛的pH范围内有效地去除阴离子染料.
- 通过低剂量 (0.4 g/L) 的BR-HCl实现了超过99%的CR去除,在五个再生周期中表现出色的性能和稳定性 (82%的容量保留).
- AAILs提供了一种绿色,轻微的修饰路径,具有中等吸附能力,而NaOH显示出有限的改善.
结论:
- 简单且低成本的HCl修饰是将BR转化为有效的吸附剂以去除离子染料的最务实的途径.
- 与AAIL和NaOH修饰相比,BR-HCl表现出优越的性能,可重复使用性和成本效益.
- 这项研究强调了修改后的BR在可持续废水处理应用中的潜力.
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