分离被动化使成本效益高的不钢耐腐蚀和脆性
Hongxu Cheng1, Hong Luo1,2, Yue Li3
1National Materials Corrosion and Protection Data Center, Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China.
Science advances
|January 28, 2026
概括
这项研究开发了一种新的不钢,使用装饰的谷物边界. 这种先进的合金显著提高了对脆性和腐蚀的抗性,这对于可持续能源应用至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 腐蚀工程 腐蚀工程
- 可持续能源 可持续能源
背景情况:
- 不钢对于可持续能源至关重要,但受到脆性和腐蚀的影响.
- 现有的合金在长期性能方面面临限制,原因是环境损伤和机械故障.
研究的目的:
- 设计一个具有成本效益的奥氏体不钢,增强对脆性和腐蚀的抗性.
- 提高相关的可持续能源应用中的材料的耐用性.
主要方法:
- 开发了一种新型的奥氏体不钢,通过装饰对粒度边界进行原子级被动化.
- 在各种酸性和性介质中评估了耐腐蚀性.
- 评估了的脆化阻力和的扩散性.
主要成果:
- 与316L不钢相比,耐腐蚀性提高了3.8倍,脆性增加了1.35倍.
- 证明了非常低的散率 (~7.8 × 10-17 m2/s),在环境温度下减轻了脆性.
- 形成了密集的被动膜,增强了盐酸,硫酸和焦环境中的耐受性.
结论:
- 用装饰的不钢在结合的腐蚀性和脆性条件下提供了卓越的耐受性.
- 这种先进的合金在日益增长的经济中是可持续和安全的基础设施的一个有希望的材料.
相关概念视频
Corrosion
28.3K
The degradation of metals due to natural electrochemical processes is known as corrosion. Rust formation on iron, tarnishing of silver, and the blue-green patina that develops on copper are examples of corrosion. Corrosion involves the oxidation of metals. Sometimes it is protective, such as the oxidation of copper or aluminum, wherein a protective layer of metal oxide or its derivatives forms on the surface, protecting the underlying metal from further oxidation. In other cases, corrosion is...
28.3K
Hydrogen Bonds
133.0K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
133.0K
Hydrogen Bonds
14.0K
A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
14.0K
Law of Segregation
77.9K
When crossing pea plants, Mendel noticed that one of the parental traits would sometimes disappear in the first generation of offspring, called the F1 generation, and could reappear in the next generation (F2). He concluded that one of the traits must be dominant over the other, thereby causing masking of one trait in the F1 generation. When he crossed the F1 plants, he found that 75% of the offspring in the F2 generation had the dominant phenotype, while 25% had the recessive phenotype.
77.9K
Corrosion of Reinforcement
576
The corrosion of steel reinforcement within concrete is a process influenced by the material's inherent properties and external factors. The high pH level of around 13, provided by calcium hydroxide present in concrete, initially protects the steel reinforcement by promoting the formation of a passive iron oxide layer on its surface.
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
576
Steel Fastening Techniques
1.3K
Steel sections can be joined together through various fastening techniques including riveting, bolting, and welding, each suitable for different structural requirements and conditions.
Rivets are cylindrical steel fasteners with a specially designed head. During application, rivets are heated until white-hot and then inserted through pre-drilled holes in the steel sections. A pneumatic hammer is used to shape the exposed end into a second head, securing the sections together.
Bolting is another...
Rivets are cylindrical steel fasteners with a specially designed head. During application, rivets are heated until white-hot and then inserted through pre-drilled holes in the steel sections. A pneumatic hammer is used to shape the exposed end into a second head, securing the sections together.
Bolting is another...
1.3K


