电荷密度不匹配是高度缩的电解质溶液和高度水溶性盐的关键特征
Jacob G Reynolds1, Hsiu-Wen Wang2, Trent R Graham3
1Central Plateau Cleanup Company, P.O. box 850, Richland, WA, USA.
概括
高度水溶性盐形成缩的溶液由于不匹配的对子离子电荷密度,而不是强的离子配对. 这种不匹配驱动了溶解度,与固体形成鲜明对比,匹配的值减少了溶解度.
科学领域:
- 化学 化学 化学
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
背景情况:
- 高溶解的电解质形成超缩的溶液,每离子含水量有限.
- 这些溶液中的离子往往形成集群,其协调球中有多个反离子.
研究的目的:
- 为了调查是否高溶解度是由于强烈的液相离子亲和力或较差的固相离子亲和力的结果.
- 为了探索 counterion 电荷密度不匹配和盐溶性的关系.
主要方法:
- 应用了债券价值模型及其价值匹配原理.
- 将 counterions 之间的电荷密度不匹配与它们对盐的溶解度进行比较.
- 与离子的平均键值相对应的绘制溶解度.
主要成果:
- 当和离子键的价值相匹配时观察到最低的溶解度.
- 对于具有差异匹配键价值的盐,观察到的最高溶解度.
- 确认的离子配对常数表明,最弱的离子配对与最大的键值不匹配有关.
结论:
- 盐的高水溶性是由不匹配的对子离子电荷密度驱动的.
- 尽管存在弱离子配对,但溶解性发生,而不是由于强离子配对.
- 价值匹配原理有效地预测基于对比子相互作用的盐溶度.
相关概念视频
Electrolyte and Nonelectrolyte Solutions
71.9K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
71.9K
Determining the pH of Salt Solutions
48.1K
The pH of a salt solution is determined by its component anions and cations. Salts that contain pH-neutral anions and the hydronium ion-producing cations form a solution with a pH less than 7. For example, in ammonium nitrate (NH4NO3) solution, NO3− ions do not react with water whereas NH4+ ions produce the hydronium ions resulting in the acidic solution. In contrast, salts that contain pH-neutral cations and the hydroxide ion-producing anions form a solution with a pH greater than 7. For...
48.1K
Expressing Solution Concentration
67.7K
A solute is a component of a solution that is typically present at a much lower concentration than the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
Concentrations may be quantitatively assessed using a wide variety of measurement units, each convenient for particular applications. Molarity (M) is a useful concentration unit for many applications in chemistry.
Concentrations may be quantitatively assessed using a wide variety of measurement units, each convenient for particular applications. Molarity (M) is a useful concentration unit for many applications in chemistry.
67.7K
Solution Concentration and Dilution
133.7K
The relative amount of a given solution component is known as its concentration. Often, though not always, a solution contains one component with a concentration that is significantly greater than that of all other components. This component is called the solvent and may be viewed as the medium in which the other components are dispersed or dissolved. Solutions in which water is the solvent are, of course, very common on our planet. A solution in which water is the solvent is called an aqueous...
133.7K
Electrolytes: van't Hoff Factor
36.6K
Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
36.6K
Mismatch Repair
43.7K
Overview
43.7K


