使用特拉赫兹光谱成像,对聚乙烯化物中的晶相转换和方向演变进行定量监测
Haokun Xiao1, Maoyuan Li2, Jianjian Huang1
1National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangzhou 510641, China.
Analytical chemistry
|January 30, 2026
概括
特拉赫兹时域光谱 (THz-TDS) 动态监测在拉伸过程中聚合物晶体的变化. 这种非破坏性方法追踪相位转换和方向,提供对材料行为的洞察力.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 频谱学是一种光谱学.
背景情况:
- 结晶聚合物转换的实时,空间分辨率的表征具有挑战性.
- 像FTIR和X射线这样的传统方法缺乏速度和空间绘图能力.
- 了解聚合物加工需要监测阶段和方向演变.
研究的目的:
- 开发一种动态的,非破坏性的方法来监测聚合物中的晶相转换和方向.
- 为了利用太赫兹时域光谱学 (THz-TDS) 进行定量结构分析.
- 在变形过程中可视化相位含量和方向的空间分布.
主要方法:
- 利用太赫兹时域光谱 (THz-TDS) 在单轴拉伸过程中对聚乙烯化物 (PVDF) 进行动态监测.
- 开发了半定量模型,将THz异性吸收与β相分数和方向相关联.
- 采用THz光谱成像用于结构演变的空间可视化.
主要成果:
- THz异性吸收与β相分数和方向参数有很强的相关性.
- THz-TDS的结果与FTIR和2D-WAXD有很好的一致性.
- 空间测绘显示,在拉伸过程中,部区域发生了增加的β相含量和方向.
结论:
- THz-TDS是一种快速,非侵入性的工具,用于监测晶体聚合物的结构异性质.
- 该技术可以可视化相位和方向演变的空间分布.
- 这种方法具有在线过程控制和聚合物物理研究的潜力.
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