铁电中过渡切换状态的原子结构
Jiawei Huang1, Jinyang Li2, Xinyue Guo3
1The Hong Kong University of Science and Technology, Department of Physics, Clear Water Bay, Hong Kong, China.
Physical review letters
|January 30, 2026
概括
在铁电化 (AlScN) 中的极化切换不涉及非极相. 相反,180度域壁表现出一个曲的形态,影响切换动态和材料特性.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 纳米技术纳米技术
背景情况:
- 铁电材料表现出自发的电极化,可以被外部电场逆转.
- 氏铁电酸 (AlScN) 是先进电子应用的一个有前途的材料.
- 了解微观切换机制对于优化铁电器件性能至关重要.
研究的目的:
- 为了阐明在氏体铁电AlScN中极化切换的原子尺度机制.
- 研究域壁形态在铁电切换动态中的作用.
- 为了将局部域壁结构与宏观铁电行为相关联.
主要方法:
- 先进的薄膜制造和表征.
- 铁电切换动态测量. 铁电切换动态测量.
- 高分辨率扫描传输电子显微镜 (STEM).
- 大规模的分子动力学模拟使用基于深度神经网络的原子间潜力.
主要成果:
- 有证据表明,STEM图像中观察到的过渡区域是 180 度域墙壁的曲的投影工件,而不是一个非极相.
- 原子学模拟显示,切换是通过集体的,一列一列的原子移位发生的,形成曲的域墙壁.
- 增加含量降低了域壁能量和核化屏障,降低了切换场.
结论:
- 在AlScN中,极化切换是通过集体的原子移位进行的,形成特征性的齐克扎克域壁.
- 域壁的内在3D齐克扎克形态,而不是短暂的非极相,解释了观察到的现象.
- 结果将局部域壁结构与AlScN的切换动态和宏观铁电性质联系起来.
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