在晶体岩石中评估矩阵扩散和吸附参数的方法:适用于Grimsel试验场实验室和现场扩散实验
Yuta Fukatsu1, Tomomi Oguri2, Takafumi Hamamoto3
1Nuclear Fuel Cycle Engineering Laboratories, Japan Atomic Energy Agency, 4-33 Muramatsu, Tokai, Ibaraki 319-1194, Japan; Horonobe Underground Research Center, Japan Atomic Energy Agency, 432-2 Hokushin, Horonobe, Hokkaido 098-3224, Japan.
Journal of contaminant hydrology
|January 30, 2026
概括
本研究开发了一种方法来测量在深层地质形成中的扩散和吸附参数,使用现场和实验室测试. 该方法准确地估计了吸附标记物的参数,并突出了影响非吸附标记物运输的因素.
科学领域:
- 地质化学 地质化学
- 水文地质学 水文地质学
- 核废物管理 核废物管理
背景情况:
- 准确的扩散和吸收参数对于深层地质处置安全评估至关重要.
- 现场测量由于实际限制而具有挑战性.
研究的目的:
- 在现实的地质条件下建立评估扩散系数 (De) 和分布系数 (Kd) 的方法.
- 整合长期现场扩散 (LTD-II) 实验与实验室扩散试验.
- 通过实验室实验验证现场参数估计.
主要方法:
- 对孔隙连接性和异型运输的芯样本的后分析.
- 数字建模,包括钻井破坏区 (BDZ).
- 实验室通过扩散实验进行参数验证.
主要成果:
- 建模成功地复制了现场枯竭曲线和跟踪器配置文件,识别了BDZ效应.
- 来自De和Kd的吸附标记物 (Na+ , Cs+ , Ba2+) 在实验室和现场条件之间一致,直至几厘米.
- 非吸收的标记物 (HTO,36-Cl) 在现场显示出更高的De,这可以通过更长距离的异构性和向导来解释.
结论:
- 综合方法提供了一种可靠的方法来导出代表现场条件的扩散和吸附参数.
- 考虑到局部结构和液压变化对于解释现场扩散数据至关重要.
- 该研究澄清了在晶体岩石中运输建模的实际局限性和适用范围.
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