对从雨水保留池中分析微塑料的样本准备的批判性观点
S Grass1, M Huber-Gedert1, C Marx1
1Microbubbles GmbH, Leipzig, Germany.
Journal of hazardous materials
|January 30, 2026
概括
为微塑料分析选择合适的化学品至关重要. 在雨水样本中使用聚酸盐 (SPT) 进行密度分离,可以比化 (ZnCl2) 更准确地量化微塑料 (MP).
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 聚合物科学 聚合物科学
背景情况:
- 在环境样本中精确检测微塑料 (MP) 是具有挑战性的,因为在样本准备过程中存在分析偏差.
- 常用方法可能导致低估MP负载,影响环境风险评估.
研究的目的:
- 系统地评估不同矩阵消化剂和密度分离介质对雨水中MP量化的影响.
- 识别分析偏差,并为准确的MP检测提出改进建议.
主要方法:
- 盐酸过酸盐 (NaOCl) 与过氧化 (H2O2) 的比较,用于矩阵消化.
- 评价化 (ZnCl2) 与聚化 (SPT) 的密度分离.
- 使用激光直接红外 (LDIR) 成像对MP的量化.
- 分析MP与矿物质的异构聚合.
主要成果:
- 与化 (ZnCl2) (66颗粒/L) 相比,聚酸盐 (SPT) 的MP负载 (125颗粒/L) 显著更高,不包括轮胎和道路磨损颗粒.
- 低密度聚合物与矿物质的异质聚合导致MP在高密度分数中丢失,特别是与ZnCl2.
- 基于SPT的协议证实了通过带有微漂浮技术的雨水保留系统有效地去除MP.
结论:
- 目前用于MP检测的分析实践,特别是密度分离,可能导致严重低估.
- 使用SPT修订的分析协议是必要的,以准确地确定环境矩阵中的MP负载.
- 在雨水保留系统中证明了有效的MP去除.
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