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从作为氧化物处理的酸性矿水中提升稀土元素的选择性回收:在结晶阶段进行实验优化
Óscar Crespo1, Mehrez Hermassi2, Oriol Gibert1
1Chemical Engineering Department, Escola d'Enginyeria de Barcelona Est (EEBE), Universitat Politècnica de Catalunya (UPC)-BarcelonaTECH, Campus Diagonal-Besós, 08930, Barcelona, 08930, Spain; Barcelona Research Center for Multiscale Science and Engineering, Campus Diagonal-Besós, Barcelona, 08930, Spain.
Journal of environmental management
|January 30, 2026
概括
从酸性矿水 (AMW) 中回收稀土元素 (REEs) 是可行的,使用氧酸盐沉. 最佳条件包括足够的氧酸剂量和1.2-3.0的pH范围,以有效地回收REE.
科学领域:
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- 酸性矿山水 (AMW) 由于大量存在,因此存在环境挑战.
- 稀土元素 (REEs) 是AMW中存在的关键原料.
- 从AMW中可持续的REE回收减轻了环境影响,并使供应多样化.
研究的目的:
- 通过氧酸盐沉来研究REE回收的最佳条件.
- 专注于代表离子交换 (IX) 度的硫酸溶液.
- 确定氧酸剂量,添加方式和pH的影响.
主要方法:
- 通过不同的关键参数进行了降水实验.
- 分析了基于参数调整的REE回收效率.
- 使用SEM-EDX和XRD进行材料表征.
主要成果:
- 氧化酸剂量显著影响REE恢复,超过80%的2倍史泰基测量要求.
- 在pH值1.2-3.0.0范围内实现最佳REE恢复 (>86%).
- 形成的REE-oxalates具有一致的形态和组成 (5-19重量%的REE).
结论:
- 制定了有效地从AMW缩物中回收REE的实践指南.
- 氧沙酸盐沉是一种可行的方法,用于从酸性溶液中回收REE.
- 优化条件提高了REE采购和环境管理的可持续性.
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