调节键以减少高稳定性金属阳极的多硫化物寄生反应性
Zheng Li1, Bo-Quan Li2, Li-Li Chen2
1Beijing Key Laboratory of Complex Solid State Batteries, Department of Chemical Engineering, Tsinghua University, Beijing, P. R. China.
Angewandte Chemie (International ed. in English)
|January 31, 2026
概括
研究人员开发了一种弱阴离子相互作用策略,以改善硫 (Li-S) 电池. 这种方法使用氨酸来减少寄生反应,使电池寿命更长,能量密度更高,用于先进的能量存储.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硫 (Li-S) 电池具有高能量密度,但遭受快速降解.
- 聚硫化物 (LiPS) 和金属阳极之间的寄生反应导致循环失效.
研究的目的:
- 引入一个弱阴离子相互作用策略,以减轻LiPS的反应性.
- 为了提高Li-S电池的循环稳定性和能量密度.
主要方法:
- 使用氨酸 (NH4+) 与LiPS相互作用,削弱它们的反应能力.
- 调节分子级相互作用以抑制寄生虫反应与金属阳极.
主要成果:
- 在苛刻的条件下,Li-S硬币电池的寿命从53周期延长到149周期.
- 在一个8Ah Li-S袋式电池中,实现了502Wh kg-1的初始能量密度,循环稳定.
- 已证明可以抑制有害的寄生虫反应.
结论:
- 建立了基于键化学的新弱阴离子相互作用策略.
- 为开发长周期,高能量密度的Li-S电池提供了可通用的方法.
相关概念视频
Bonding in Metals
52.4K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.
52.4K
Metal-Ligand Bonds
24.3K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
24.3K
Alkali Metals
24.6K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
24.6K
Ionic Bonding and Electron Transfer
49.1K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
49.1K
Bond Energies and Bond Lengths
31.5K
Stable molecules exist because covalent bonds hold the atoms together. The strength of a covalent bond is measured by the energy required to break it, that is, the energy necessary to separate the bonded atoms. Separating any pair of bonded atoms requires energy — the stronger a bond, the greater the energy required to break it.
31.5K
Batteries and Fuel Cells
30.9K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
30.9K


