在生物基液体燃料的NiMn/NC催化剂上,素衍生生物油的氧化
Xiaomeng Yang1, Jianping Li2, Yuandong Xu3
1Institute of Biomass Science and Engineering, Henan University of Technology, Zhengzhou 450001, China; College of Food Science and Engineering, Henan University of Technology, Zhengzhou 450001, China.
Bioresource technology
|January 31, 2026
概括
这项研究引入了一种新的NiMn/NC催化剂,用于高效的素生物油脱氧. 该过程实现了高瓜亚科尔转化,并产生了升级的生物油,适合作为可再生液体燃料.
科学领域:
- 催化剂是一种催化剂.
- 可再生能源可再生能源是可再生能源.
- 绿色化学 绿色化学
背景情况:
- 来自红素的生物油需要去氧化才能作为石油替代品使用.
- 传统的水解氧化 (HDO) 面临着高H2压力和贵金属催化剂的挑战.
研究的目的:
- 调查NiMn/NC催化剂对于素衍生化合物的in-situHDO的有效性.
- 开发一种更可持续,更有效的生物油升级方法.
主要方法:
- 使用NiMn/NC催化剂进行瓜亚科尔的氧化 (HDO),瓜亚科尔是一种素模型化合物.
- 在150°C使用水/异醇溶剂系统.
- 应用了催化剂来升级真正的素油.
主要成果:
- 实现了95.44%的瓜亚科尔转化和81.89%的脱氧产品 (环醇,环素) 的选择性.
- 从真正的素油生产了143.2%的升级生物油,其产量为14.32%和1.71%的高H/C比.
- 通过催化剂支持特性和-氧空置接口,确定了HDO的协同促进.
结论:
- 尼Mn/NC催化剂提供了一种先进的策略,用于有效地在生物油的现场HDO.
- 这种基于的催化方法有助于将生物油转化为可行的生物基液体燃料.
- 这些发现有助于从素生物质中生产可持续燃料.
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