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相关概念视频

Voltaic/Galvanic Cells02:47

Voltaic/Galvanic Cells

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Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
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Ions and Ionic Charges03:27

Ions and Ionic Charges

79.1K
In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
79.1K
Genetics of Speciation02:16

Genetics of Speciation

21.2K
Speciation is the evolutionary process resulting in the formation of new, distinct species—groups of reproductively isolated populations.
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Speciation Rates01:07

Speciation Rates

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Overview
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Ionic Radii03:10

Ionic Radii

33.5K
Ionic radius is the measure used to describe the size of an ion. A cation always has fewer electrons and the same number of protons as the parent atom; it is smaller than the atom from which it is derived. For example, the covalent radius of an aluminum atom (1s22s22p63s23p1) is 118 pm, whereas the ionic radius of an Al3+ (1s22s22p6) is 68 pm. As electrons are removed from the outer valence shell, the remaining core electrons occupying smaller shells experience a greater effective nuclear...
33.5K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

20.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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相关实验视频

Updated: Feb 2, 2026

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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通过离子分类工程调节热扩散/联,使高性能离子热电电池成为可能.

Yuchen Li1, Ying-Ru Qiu2, Jinsha Liao3

  • 1Department of Mechanical Engineering, The University of Hong Kong, Hong Kong, China.

Nature communications
|January 31, 2026
PubMed
概括

研究人员在PVA-CuCl2凝中发现了一种新的离子热电 (i-TE) 合效应. 这种相互作用增强了热电转换,为自动供电的电子设备实现了巨大的-30.6 mV/K的热电力.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 收集能源 收集能源

背景情况:

  • 离子热电 (i-TE) 材料为自动供电的电子产品提供了收集低等级热的潜力.
  • 在n型材料中合多个i-TE效应是有限的,阻碍了高性能系统的开发.

研究的目的:

  • 在i-TE材料中发现和描述一种新的热氧还氧反应.
  • 研究热和热扩散贡献之间的互动合效应.
  • 建立基于协调化学的高性能i-TE材料的设计原则.

主要方法:

  • 操作特征技术来追踪反应过程.
  • 对离子物种化和协调物种的定量分析.
  • 聚乙烯醇 (PVA) -CuCl2凝系统的制造和测试.

主要成果:

  • 通过Cl-稳定Cu2+和Cu+之间的被忽视的热氧还氧反应被确定.
  • 在PVA-CuCl2凝中验证了由离子特异驱动的交互性i-TE合效应.
  • 通过调节离子物种化,获得了-30.6 mV/K的巨大热力和0.6 mW/m2K2的功率密度.
  • 16个细胞的i-TE模块从15K的温度差异中产生3.5V和22μW.

结论:

  • 协调化学在交互式热扩散/联合效应中起着至关重要的作用.
  • 调离子特异化为提高i-TE材料性能提供了一个可行的策略.
  • 发现的合效应为可持续的能源采集提供了先进的i-TE材料的新设计原则.