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相关概念视频

Hydrogen Bonds00:26

Hydrogen Bonds

133.3K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
133.3K
Atomic Orbitals02:44

Atomic Orbitals

43.9K
An atomic orbital represents the three-dimensional regions in an atom where an electron has the highest probability to reside. The radial distribution function indicates the total probability of finding an electron within the thin shell at a distance r from the nucleus. The atomic orbitals have distinct shapes which are determined by l, the angular momentum quantum number. The orbitals are often drawn with a boundary surface, enclosing densest regions of the cloud.
43.9K
The Atomic Theory of Matter02:59

The Atomic Theory of Matter

128.0K
The earliest recorded discussion of the basic structure of matter comes from ancient Greek philosophers. Leucippus and Democritus argued that all matter was composed of small, finite particles that they called atomos, meaning “indivisible.” Later, Aristotle and others came to the conclusion that matter consisted of various combinations of the four “elements” — fire, earth, air, and water — and could be infinitely divided. Interestingly, these philosophers...
128.0K
Hybridization of Atomic Orbitals I03:24

Hybridization of Atomic Orbitals I

67.3K
The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
67.3K
Hybridization of Atomic Orbitals II03:35

Hybridization of Atomic Orbitals II

49.0K
sp3d and sp3d 2 Hybridization
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Acid/Base Strengths and Dissociation Constants03:02

Acid/Base Strengths and Dissociation Constants

69.8K
The relative strength of an acid or base is the extent to which it ionizes when dissolved in water. If the ionization reaction is essentially complete, the acid or base is termed strong; if relatively little ionization occurs, the acid or base is weak. There are many more weak acids and bases than strong ones. The most common strong acids and bases are listed below:
69.8K

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相关实验视频

Updated: Feb 3, 2026

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

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如何N-Doping促进在基于石墨烯的单原子催化剂中的解离.

Safouan Ziat1, Florian Brix1, Arshak Tsaturyan1

  • 1Univ. de Lorraine, CNRS UMR7198, Institut Jean Lamour, Campus Artem, 2 allée André Guinier, 54000 Nancy, France.

The journal of physical chemistry letters
|February 2, 2026
PubMed
概括

用剂合的石墨烯单原子催化剂在化方面表现有前途. 这项研究揭示了这些催化剂上的解离机制,这对于设计用于储存和进化反应的先进材料至关重要.

科学领域:

  • 催化剂是一种催化剂.
  • 材料科学 材料科学 材料科学
  • 表面化学 表面化学

背景情况:

  • 用添加的石墨烯单原子催化剂 (SAC) 对选择性化和储存具有前景.
  • 了解这些SAC上的进化机制至关重要,但具有挑战性.

研究的目的:

  • 系统地研究M-C3-xNx活性位点 (M=Co,Ni,Pd;x=0-3) 上的吸附和解离能.
  • 根据含量阐明控制解离的独特机制和激活障碍.

主要方法:

  • 吸附和解离能量的第一原理计算.
  • 在各种配合石墨烯SAC模型上分析解离路径 (异溶性和同溶性).
  • 调查布伦斯特德-埃文斯-波兰尼扩展关系的激活障碍.

主要成果:

  • 分离通常是内热的,除了Pd-N3和Pd-CN2位点.
  • 贫部位有利于具有高激活能 (0.6-1.1 eV) 的异质解离,除了Pd-C2N (0.37 eV).
  • 富含的地点有利于具有低激活障碍 (<0.4 eV) 的同解解离,尽管Ni-N3由于电子封闭而表现出重组.

结论:

  • 对N-化石墨烯SACs上的解离机制有了详细的了解.

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  • 在所有模型中都观察到布伦斯特德-埃文斯-波兰尼缩放.
  • 结果为设计针对特定催化应用的定制SAC提供了洞察力,包括的演化和储存.