含有Ni/Co-预催化剂的牺牲MoO:了解氧电催化在稳定状态条件下的活性结构和Fe动力学
Indranil Mondal1, Anisha Mondal1, Anumod C A1
1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram (IISER-TVM), Thiruvananthapuram, 695551 Kerala, India. indraiict@gmail.com.
Nanoscale
|February 2, 2026
概括
微量铁 (Fe) 在氧化水中的 (Ni) 和 (Co) 催化剂中至关重要. 对于持续的氧化演化反应 (OER) 活动和催化剂耐用性而言,最低限度的可补充Fe供应至关重要.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- (Ni) 和 (Co) 催化剂对于性介质中的氧化演化反应 (OER) 是至关重要的.
- 为了持续的催化,以最小的微量铁 (Fe) 增强OER活动是经济上可取的.
研究的目的:
- 用Ni/CoMoO4.4来确定长期氧化水所需的最低Fe含量.
- 在OER期间调查重建的Ni和Co相内的Fe动态.
主要方法:
- 使用Ni/CoMoO4作为预催化剂,在性电解质中进行两阶段重建.
- 在含有Fe和无Fe的电解质中采用了交替循环,以研究Fe的动态.
- 在现场应用拉曼光谱来监测氧化还原中心和Fe相互作用.
主要成果:
- 在无形的Ni(O) OH (表面局部化) 和晶体Co(O) OH (更稳定) 之间,铁的结合有所不同.
- 连续的Fe溶解-重新沉积周期直接影响催化活性.
- 在Fe操作电位观察到的Ni3+和Co4+氧化还原中心的出现.
结论:
- 微量但可补充的Fe3+供应对于高OER性能至关重要.
- 铁的动态显著影响了催化剂的长期耐用性和水氧化效率.
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