放射性-137从污染的废水中去除,使用从大麻根茎中提取的生物基活性碳,增强了铜基酸
Kanyanat Tawatbundit1, Sudarat Issarapanacheewin1, Witsanu Katekaew1
1Nuclear Safety Technology and Radioactive Waste Management Center, Thailand Institute of Nuclear Technology (Public Organization) Ongkharak Nakhon Nayok 26120 Thailand sudarat@tint.or.th.
RSC advances
|February 2, 2026
概括
研究人员开发了一种新型的活性碳复合物,该复合物来自麻豆根茎和铜六化酸盐,用于从废水中去除放射性-137. 这种材料实现了超过99%的去除效率,为环境修复提供了有前途的解决方案.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 放射化学 放射化学是指辐射化学.
背景情况:
- 废水中的放射性-137 (Cs-137) 污染对环境和健康构成重大风险.
- 从复杂的矩阵中去除Cs-137的有效方法,如真正的废水,对于公共安全和生态保护至关重要.
研究的目的:
- 合成和描述从麻豆根茎 (CRAC) 中获得的活性碳,与铜基酸盐 (CuHCF) 复合.
- 评估CuHCF/CRAC复合物在实际废水中去除Cs-137的效率.
- 研究影响Cs-137吸附和复合材料可重复使用的因素.
主要方法:
- 香草根茎被用高酸 (KMnO4) 进行水热碳化,并被烧解以产生CRAC.
- CuHCF纳米粒子通过水热方法与CRAC进行合成和复合,以形成CuHCF/CRAC复合材料.
- 进行了批量吸附实验,使用加Cs-137 (10,000 Bq L-1) 的真实废水进行了批量吸附实验,以评估清除效率和优化复合材料成分 (5% w/w KMnO4).
主要成果:
- 优化的CuHCF/CRAC(5) 复合物实现了超过99%的Cs-137去除效率.
- 通过引入功能组 (芳香,,碳酸盐) 来增强KMnO4处理的吸附,这些功能组改善了与Cs+离子的静电相互作用.
- 吸附遵循弗洛伊德利希异热模型和伪二次动力学,具有出色的可重复使用性 (>在5个周期内97%的去除率) 和在中性至性pH下增强的性能.
结论:
- 合成的CuHCF/CRAC复合物显示出Cs-137从真实废水中去除的高效率和选择性.
- 该材料在特定条件下表现出优异的稳定性,可重复使用性和有利的吸附特性.
- 这种新型复合物显示出在放射性废水处理和环境修复方面的实际应用的巨大潜力.
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