可持续的烟火技术:用于延迟组合的B4C/Bi2O3的燃烧行为
Danillo F Vianna Cantini1, Vojtěch Pelikán1, Eva Schmidová2
1Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Studentská 95, Pardubice 532 10, Czech Republic.
ACS omega
|February 2, 2026
概括
本研究研究碳化物 (B4C) 和 bismuth (III) 氧化物 (Bi2O3) 作为可持续的烟火延迟化合物. 更高的压缩通过限制孔隙性来降低燃烧速度,优化更绿色的配方.
科学领域:
- 材料科学 材料科学 材料科学
- 燃烧化学 燃烧化学是什么
- 绿色化学 绿色化学
背景情况:
- 开发可持续的烟火延迟成分对于环境和性能进步至关重要.
- 传统配方通常依赖于不那么环保的成分.
- 碳化物 (B4C) 和 bismuth (III) 氧化物 (Bi2O3) 提供了有希望的绿色替代品.
研究的目的:
- 为了探索B4C/Bi2O3烟火组合的燃烧行为.
- 了解压缩压力和颗粒/颗粒粒大小对燃烧速度的影响.
- 阐明这些绿色配方的多阶段反应途径.
主要方法:
- 用于配方设计的热力学计算.
- 在不同压力下 (64-385 MPa) 颗粒和压制组合物.
- 燃烧速度分析,固体残留物检查和燃气分析.
主要成果:
- 增加的压缩压力逐渐降低了燃烧速度,由于孔隙性减少.
- 颗粒和颗粒大小显著影响了燃烧行为和燃烧概况.
- 反应机制涉及不同的固体-固体,固体-液体和气相.
结论:
- B4C/Bi2O3配方证明了作为环保型烟火材料的可行性.
- 压缩压力是控制这些绿色成分燃烧速度的关键参数.
- 了解多阶段反应途径可以优化性能并减少对环境的影响.
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