由固体-液体界面能量驱动的Al-Zn树突的图案形成
Lele Chen1, Chenglin Huang1, Fang Luo1
1State Key Laboratory of Advanced Special Steel, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China.
Langmuir : the ACS journal of surfaces and colloids
|February 2, 2026
概括
本研究量化了Al-Zn合金中的固体-液体界面能量异质性. 这种异构性影响微观结构的进化,导致复杂的,在凝固过程中超分支的树形状.
科学领域:
- 材料科学 材料科学 材料科学
- 固化科学 固化科学
- 晶体学 晶体学是指结晶学.
背景情况:
- 固体-液体界面能量对于相位过渡期间的材料特性至关重要.
- 了解界面能量异构性是控制微观结构演变的关键.
- 合金作为研究凝固现象的模型系统.
研究的目的:
- 量化描述Al-30重量% Zn合金中固体-液体界面能量的异质性.
- 为了将界面能量异质性与特定的树突形态的形成联系起来.
- 为Al-Zn合金的形态不稳定性提供机械洞察力.
主要方法:
- 利用改进的平衡形状方法进行界面能量分析.
- 采用X射线微计算机断层扫描 (CT) 进行3D微结构可视化.
- 应用的数字图像分析与富里埃数列和立方波对异性变量参数提取.
主要成果:
- 确定了二维和三维异构性参数 (ε4, ξ1, ξ2).
- 沿100和110方向确定了最大的界面能量.
- 沿100和110方向观察到最小的界面刚度,与超分支形态相关.
结论:
- 界面能量异质性直接影响着树形状的形成.
- 100和110方向之间的硬度几乎相当,促进了形态不稳定性.
- 这项研究提供了定量证据,证明了界面异构在固化中的作用.
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