相关实验视频
Updated: Feb 5, 2026

06:15
Preparation of Binary and Ternary Deep Eutectic Systems
Published on: October 31, 2019
12.8K
直接的压电效应在深层环氧溶剂中的直接压电效应
Allison M Stettler1, Sheryl S Blanchard1, Gary A Baker2
1Michigan State University, Department of Chemistry, East Lansing, Michigan 48824, United States.
Journal of the American Chemical Society
|February 3, 2026
概括
深度浸泡溶剂 (DES) 呈现出直接的压电反应,类似于离子液体. 这一发现表明,DES可以通过调整其组件来设计可调节的压电应用.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 在某些液体材料中已知压电效应,即从机械应力产生电力.
- 室温离子液体 (RTIL) 由于压力诱导的相位过渡而表现出压电性.
- 深度浸泡溶剂 (DES) 是一种具有可调节性质的材料.
研究的目的:
- 在四个特定的DES中研究直接压电反应.
- 确定这些DES的压电系数 (d33).
- 为了比较DESs与RTILs的压电行为.
主要方法:
- 直接测量在施加力下产生的电流.
- 四种DES的表征:胆化物:乙烯基醇 (ChCl:EG),胆化物:甘油 (ChCl:Gly),胆化物:1,3-二醇 (ChCl:PD) 和胆化物:尿素 (ChCl:urea).
- 分析力-电流关系以确定压电系数 (d33).
主要成果:
- 所有四个研究的DES都显示出直接的压电反应.
- 在施加的力和产生的电流之间观察到一个线性关系.
- 对于DES的压电系数 (d33) 值与RTIL的值相似.
结论:
- 压电效应是DES中观察到的一般现象,不仅限于RTIL.
- 德斯为可调节的压电应用提供了潜力.
- 选择和DES成分的比例可以影响压电反应.
相关概念视频
Solvents
71.2K
A solvent is a substance, most often a liquid, that can dissolve other substances. Here, the substance being dissolved is called a solute. When a solvent and a solute combine, they form a solution - a homogenous mixture of both the solvent and the solute. Water is a universal biological solvent. Its polar structure allows it to dissolve many other polar compounds. The ability of water to dissolve is governed by a balance between water molecules binding to each other and binding to the solute.
A...
A...
71.2K
Titration in Nonaqueous Solvents
1.4K
Most acid-base titrations are performed in an aqueous medium. In aqueous titrations, water competes with weaker acids or bases for proton donation or acceptance, leading to ambiguous endpoints in the titration curve. Water also affects the partial ionization of weak acids or bases. For example, water accepts a proton from acetic acid to form hydronium and acetate ions. The hydronium ion formed is a stronger acid than acetic acid, and the acetate ion is a stronger base than water. As a result,...
1.4K
Directing Effect of Substituents: meta-Directing Groups
6.0K
Substituents on the benzene ring that direct an incoming electrophile to undergo substitution at the meta position are called meta directors. All meta directors either have a positive charge on the atom directly bonded to the ring or a partial positive charge. These groups function by withdrawing electrons from the ring through inductive and resonance effects. Consider the carbocation intermediates formed upon the addition of an electrophile on nitrobenzene at the...
6.0K
Chemical Shift: Internal References and Solvent Effects
1.4K
In an NMR sample, precise measurement of the absolute absorption frequencies of nuclei is difficult. A standard internal reference compound is added, and the frequency difference between the reference signal and sample signals is measured.
The internal reference compound generally used in NMR spectroscopy is tetramethylsilane (TMS). TMS is preferred because it is chemically inert, soluble in NMR solvents, and easily removable. Also, the highly shielded methyl protons in TMS yield an intense...
The internal reference compound generally used in NMR spectroscopy is tetramethylsilane (TMS). TMS is preferred because it is chemically inert, soluble in NMR solvents, and easily removable. Also, the highly shielded methyl protons in TMS yield an intense...
1.4K
Directing Effect of Substituents: ortho–para-Directing Groups
8.5K
Ortho–para directors are substituent groups attached to the benzene ring and direct the addition of an electrophile to the positions ortho or para to the substituent. All electron-donating groups are considered ortho–para directors. They donate electrons to the ring and make the ring more electron-rich. The ring is therefore susceptible to the addition of electrophiles. Substituents such as amino, hydroxy, or alkoxy, containing lone pairs on the atom adjacent to the ring, donate...
8.5K
Directional Terms
16.5K
Directional terms are essential for describing the relative locations of different body structures. For instance, an anatomist might describe one band of tissue as "inferior to" another, or a physician might describe a tumor as "superficial to" a deeper body structure. These terms often use comparative terms in pairs to trace out the relative locations of one body part to another or descriptions of body tissues like the deeper ones from superficially present with reference to...
16.5K

