用于选择性吸附的功能化聚基甲酸:实验和理论计算见解
Ahmad A Tolba1, Ebrahium Abdel Gwad1, Marwa M Rashad1
1Nuclear Materials Authority P.O. Box 530, El-Maadi Cairo Egypt A_orabi_chem@yahoo.com.
RSC advances
|February 4, 2026
概括
一种新型的聚氨酸-酸功能化聚甘油甲基酸盐 (PPA-PGMA) 吸收剂有效地从酸性溶液中回收. 这种耐用吸附剂具有很高的选择性和可重复使用性,为从矿石浸出物中提取提供了一个有前途的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 核化学 核化学 核化学
背景情况:
- 回收对核能和工业至关重要.
- 现有的方法面临效率,选择性和环境影响方面的挑战.
- 为了有效提取,需要开发先进的吸附剂.
研究的目的:
- 为了合成和表征一种新的功能化吸附剂,PPA-PGMA,用于回收.
- 研究PPA-PGMA的吸附机制,动力学,热力学和可重复使用性.
- 为了评估吸附剂在从真正的矿石浸出物中回收的性能.
主要方法:
- 合成PPA-PGMA吸附剂和结构特征 (CHNP,BET,SEM,TGA,XRD,XPS,FTIR) 的合成.
- 批量吸附实验以确定最佳条件 (pH,时间) 和吸附能力.
- 动力学,热力学和脱落研究;对酸性矿石液的应用.
主要成果:
- 在pH值3.0-6.0的情况下,PPA-PGMA表现出高和吸附能力,为U (VI) 的0.828mmolg-1在pH值3.0-6.0.
- 吸附遵循伪二次动力学和兰格穆尔异热,表明一个自发的,内热过程.
- 吸附剂在六个循环后保持了88-90%的效率,并且在矿石浸出物中对U (VI) 的选择性很高.
结论:
- PPA-PGMA是一种高效,可重复使用和选择性吸附剂,用于回收.
- 开发的3D非线性数学模型准确地描述了吸附过程.
- 在从复杂的酸性矩阵中提取时,PPA-PGMA具有显著的实际应用潜力.
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