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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
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Chemical substances interact in many different ways. Certain chemical reactions exhibit common patterns of reactivity. Due to the vast number of chemical reactions, it becomes necessary to classify them based on the observed patterns of interaction.
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Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
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A conductor needs to be a component of a path that creates a closed loop or full circuit to have a continuous current flowing through it. A current starts to flow if an electric field is created inside an isolated conductor that is not part of a full circuit. The conductor quickly develops a net positive charge at one end and a net negative charge at the other. These charges generate an electric field opposite the direction of the applied electric field, which reduces the current. Eventually,...
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对于水性电池的电解质设计.

Hu Hong1, Qingshun Nian1, Xun Guo1

  • 1Department of Materials Science and Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong 999077, China.

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水性电池提供安全和负担得起的能量存储,但面临着低压限制. 本综述详细介绍了先进的水性电解质的分子设计原理,以提高电网规模应用的能量密度.

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科学领域:

  • 电化学 电化学 电化学
  • 材料科学 材料科学 材料科学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 由于安全性,简单性和成本,水性电池对电网规模的储能充满希望.
  • 低输出电压限制了当前水性电池系统的能量密度.
  • 水性电解质对于离子运输和界面反应至关重要,影响整体性能.

研究的目的:

  • 为了解决水性电解质在提高电池能量密度方面的局限性.
  • 为了阐明水性电解质设计中的核心瓶.
  • 概述先进的水性电解质的实践实施的分子级设计原则和途径.

主要方法:

  • 关于水性电解质设计的当前文献的综述.
  • 分析调节离子运输和界面反应的分子层次机制.
  • 确定关键挑战和未来的研究方向.

主要成果:

  • 在水性电解质设计中确定了阻碍能量密度的核心瓶.
  • 为电解质优化提炼了基本的分子级设计原则.
  • 概述了开发下一代水性电解质的可行策略.

结论:

  • 水性电解质设计的进步对于提高电池性能至关重要.
  • 开发具有协调电化学性质的电解质将加速实际应用.
  • 这项工作指导了用于转型能源解决方案的高性能水性电解质的开发.