通过控制的聚合和薄膜形成动力学,使高效的有机太阳能电池能够使用低成本的线性合聚合物
Bingyan Yin1,2, Zhili Chen1,2,3, Baoqi Wu4,5
1Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, P. R. China.
研究人员开发了用于有机光伏的简单,高性能聚合物供体. 对聚合物聚合和兼容性的精确控制导致设备的功率转换效率达到20.42%.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 在有机光伏中,结构简单的聚合物捐赠者通常表现不佳.
- 优化活性层形态对于高性能设备至关重要.
研究的目的:
- 调查受控聚合物聚合和捐赠者-接受者兼容性对有机光伏性能的影响.
- 设计和合成线性合聚合物,以增强活性层形态.
主要方法:
- 合成了三种带有系统化骨干的线性合聚合物.
- 研究的聚合物聚合趋势和表面张力.
- 分析了膜形成动力学和与BTP-eC9.9的捐赠者-接受者的兼容性.
- 使用顺序沉积制造的有机光伏设备.
主要成果:
- PTTz-Cl50显示出理想的聚合和与BTP-eC9.9的最佳兼容性.
- 实现了具有适当域大小和相纯度的双连续互穿网络形态.
- 观察到快速的刺激子解离,高效的电荷传输和抑制的重组.
- 实现了20.42%的功率转换效率.
结论:
- 精确控制聚合物聚合和捐赠者-接受者兼容性是优化有机光伏活性层形态的关键.
- 开发的线性合聚合物为低成本,高效的有机光伏设备提供了一个有希望的途径.
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