在地下热处理过程中煤炭中孔隙结构的演变:实验性调查
Shizhuang Yang1,2, Song Li3,4, Wei Hou5,6
1School of Energy Resources, China University of Geosciences (Beijing), Beijing, 100083, PR China.
Scientific reports
|February 5, 2026
概括
地下煤炭热处理 (UCTT) 改变了煤炭孔状结构,增加了表面积和微孔体积. 较高的温度增强了孔隙连接,支持了二氧化碳储存潜力.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 碳捕获和储存是碳的捕获和储存.
背景情况:
- 地下煤热处理 (UCTT) 是一种新兴的技术,用于更清洁的煤炭利用.
- 由UCTT生产的火溶性炭显示了储存二氧化碳的潜力.
- 在UCTT过程中了解煤孔结构演变对于优化这一过程至关重要.
研究的目的:
- 调查UCTT期间煤孔结构和碎形特征的动态变化.
- 建立基于热处理温度的毛孔进化模型.
- 为优化二氧化碳储存UCTT操作参数提供理论基础.
主要方法:
- 在0-600°C的温度下处理的煤样品的系统检查.
- 使用了低温CO2吸附,低温N2吸附和侵入孔径学.
- 分析了毛孔体积,特定表面积和碎形尺寸的变化.
主要成果:
- 毛孔总体积最初减少,然后增加;总特定表面积随着温度的不断增加.
- 微孔体积和表面积增加,而中孔体积和表面积减少.
- 碎形尺寸表明表面粗性和复杂性的变化,并确定了孔隙演变的不同阶段.
结论:
- UCTT显著改变了煤孔结构,有利于在更高的温度 (600°C) 下微孔和巨孔的发展.
- 在更高的温度下增加的特定表面积和增强的孔隙连接性对二氧化碳储存有好处.
- 这项研究提供了一个为优化UCTT参数至关重要的三阶段毛孔演化模型.
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