在薄的Mo薄膜中进行晶格应变放松,在MgO单晶上以异质表皮生长
Petr Cejpek1, Mykhaylo Motylenko1, David Rafaja1
1Institute of Materials Science, TU Bergakademie Freiberg, Gustav-Zeuner-Str. 5, D-09599Freiberg, Germany.
概括
薄膜中的晶格菌株通过脱位和结对而放松,主要的机制取决于薄膜-基板方向. 这一过程减少了变形能量,特别是在较小的晶体中.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 薄膜技术 薄膜技术
背景情况:
- 在氧化 (MgO) 基板上的 (Mo) 薄膜的异质增长引入了由于不合适而导致的格子应变.
- 了解应变松对于控制薄膜的特性至关重要.
研究的目的:
- 为了研究在不同MgO方向上生长的Mo薄膜中晶格应变放松的机制.
- 为了确定基板的方向如何影响应变放松通路.
主要方法:
- 磁喷射用于Mo薄膜沉积.
- 用X射线衍射 (XRD) 和电子衍射进行结构和方向分析.
- 传输电子显微镜 (TEM) 用于微观结构的表征.
主要成果:
- 在 (001) 和 (011) MgO上确定了Mo薄膜的特定晶体学方向关系.
- 观察到格子应变超过弹性极限,通过位移,滑动和结合激活放松.
- 确定主导的放松机制 (位移与结合和位移) 随着基质方向的变化而变化.
- 由于晶石尺寸小,注意到额外的应变减少.
结论:
- 在异质皮质Mo膜中,格子应变放松主要是由位移和结合驱动的.
- 膜和MgO基板之间的特定方向关系决定了主要的放松机制.
- 水晶石的大小在进一步降低变形能量方面发挥着作用.
关键词:
在X射线中,X射线的衍射效果是不同的.结晶石组方法的方法电子衍射的电子衍射方式异质表皮性氧 (heteroepitaxy) 是一种格子不适合格子不适合导向关系是指导关系.压力放松放松 压力放松薄膜是一种薄膜.传输电子显微镜的使用更多相关视频
08:00Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
11.6K
04:51Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
Published on: July 8, 2021
3.2K
相关概念视频
Lattice Centering and Coordination Number
11.7K
The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
Types of Unit Cells
Imagine taking a large number of identical...
11.7K
Ionic Crystal Structures
17.1K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
17.1K
Trends in Lattice Energy: Ion Size and Charge
26.8K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
26.8K
Bewley Lattice Diagram
1.5K
The Bewley lattice diagram, developed by L. V. Bewley, effectively organizes the reflections occurring during transmission-line transients. It visually represents how voltage waves propagate and reflect within a transmission line, making it easier to understand the complex interactions that occur.
1.5K
Relaxation of Skeletal Muscles
5.9K
The period of muscle contraction primarily influences the duration of stimulation at the neuromuscular junction (NMJ), the presence of free calcium ions in the sarcoplasm, and the availability of energy or ATP to support contractions.
When an action potential reaches the axon terminal, it depolarizes the membrane and opens voltage-gated sodium channels. Sodium ions enter the cell, further depolarizing the presynaptic membrane. This depolarization causes voltage-gated calcium channels to open....
When an action potential reaches the axon terminal, it depolarizes the membrane and opens voltage-gated sodium channels. Sodium ions enter the cell, further depolarizing the presynaptic membrane. This depolarization causes voltage-gated calcium channels to open....
5.9K
Crystal Growth: Principles of Crystallization
5.0K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
5.0K
![Measuring the Spin-Lattice Relaxation Magnetic Field Dependence of Hyperpolarized [1-13C]pyruvate](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59399.jpg&w=3840&q=50)