无形转化为晶体转化:一种机械化学途径,可以实现与胺结合的共价有机框架
Normanda Brown1, Yogendra Nailwal1, Tyra Blair1
1Department of Chemistry, Clark Atlanta University Atlanta Georgia 30314 USA xli1@cau.edu.
概括
固态机械化学使无形转化为晶体转化,用于合成 imine-linked 共价有机框架 (COF). 这条绿色通道迅速创造出多样化的COF,包括以前无法进入的结构.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 超分子化学 超分子化学
背景情况:
- 无形转化为晶体转化对于共价有机框架 (COFs) 的合成至关重要.
- 固态机械化学为COF结晶提供了一个尚未探索的途径.
研究的目的:
- 建立一种机械化学途径,从无形前体中合成因胺结合的COF.
- 探索固态机械化学在COF构造中的潜力.
主要方法:
- 在环境条件下对无形COF原始体进行球磨.
- 基于 imine 的模型化合物的机械化学"杂"反应,以评估键的可逆性.
主要成果:
- 在一小时内合成了九种不同的 imine-linked COF,具有各种拓 (hcb, sql, kgm, dia) 和维度.
- 通过*de novo*机械合成无法成功合成一种高度结晶的,多孔的基于烯的COF.
- 证实了固态内存债券的高可逆性,对于纠正错误至关重要.
结论:
- 机械化学为COF合成中的无形转化为晶体转化提供了有效,通用和绿色的途径.
- 这种方法有助于构建多种COF,包括以前无法访问的COF.
- 胺基键的高可逆性是这种机械化学方法成功的关键.
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