在Nb0.8Ti0.2FeSb中通过PbI2-驱动的多层次缺陷工程实现高热电性能
Panpan Peng1, Zhihao Li1, Jianhong Hu1
1School of Physics, State Key Laboratory of Crystal Materials, Shandong University, Jinan, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|February 6, 2026
概括
这项研究引入了一种新的方法,使用可化化合物在NbFeSb半海斯勒合金中创建分层结构. 这大大降低了导热率,同时提高了机械和热电性能.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 热电学是一种热电学.
背景情况:
- 基于NbFeSb的半Heusler合金具有良好的电气和机械性能,但受到高晶格导热率的限制.
- 由于复杂的微观结构的高温加工要求,降低这些合金的导热性是具有挑战性的.
研究的目的:
- 开发一种方法,在NbFeSb合金中创建层次的微结构,以减少热导率.
- 研究这些微观结构对热电和机械性能的影响.
主要方法:
- 在Nb0.8Ti0.2FeSb的球磨过程中,PbI2的融入.
- 在高温烧结过程中PbI2的升华,形成等级结构.
- 微结构的表征,热导率,电导率,功率因子和机械性能.
主要成果:
- 形成了包括PbI2纳米相,核心孔@Pb结构,多尺度孔隙性和Fe空缺的等级结构.
- 网格的导热率降低了32%,至3.34 W m-1 K-1 在973 K,这是由于全频谱的声子散射和网格软化.
- 功率系数达到52.7μW cm-1 K-2 (zT ~ 1) 的电导率得到改善.
- 压力强度增加了38%,达到1132 MPa,微硬度达到950 HV.
结论:
- 可降解化合物有效地在高温热电学中创建分层架构.
- 这种方法同时提高了热电效率和机械强度.
- 开发的方法为先进的热电材料提供了一条途径.
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