迈向高性能超级电容器:来自溶剂分成的素的电极具有增强的活性
Hongmin Pan1, Yuhao Yan1, Daxin Jiang1
1MOE Engineering Center of Forestry Biomass Materials and Bioenergy, Beijing Forestry University, Beijing, 100083, China; Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing, 100083, China.
International journal of biological macromolecules
|February 6, 2026
概括
树木中分离的红素可以提高超级电容器的性能. 以乙分离的素为基础的树脂碳材料 (ALPFC) 显示出优越的电容和稳定性,为储能材料提供了绿色途径.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 绿色化学 绿色化学
背景情况:
- 宁的富含氧气的基团增强了超级电容器的潜力,但它的异质性阻碍了工业使用.
- 开发可持续和高性能电极材料对于先进的能源存储至关重要.
研究的目的:
- 将树木的木质素分成部分,以提高其反应性和可加工性.
- 为超级电容应用合成和评估基于素的烯酸树脂衍生碳材料.
- 为了优化素替代比率,提高电化学性能.
主要方法:
- 用溶剂提取和分离树木木质素.
- 合成基于木质素的烯酸树脂碳材料,具有不同的木质素替代.
- 碳材料的特性,包括特定表面积 (BET) 和电化学性能 (电容,循环稳定性).
主要成果:
- 分解降低了素的分子量和多分散性,增加了反应性.
- 最优的材料,ALPFC (40%的素替代),实现了高表面积 (3210 m2·g-1) 和特定电容 (335.5 F/g).
- ALPFC表现出卓越的循环稳定性 (在10,000个循环后保持110.88%) 和双电极性能 (98.15%的保留).
结论:
- 分裂性素是高性能超级电容器电极材料的可行前体.
- 基于素的烯酸树脂碳材料为传统材料提供了绿色和高效的替代品.
- 这项研究提出了一种可持续的方法,用于储能应用中的素价值化.
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