热带土壤中的元素再分配:在长期使用石膏后对REE,U和Th流动性的洞察
Luís Paulo P Tanure1, Isabela C F Vasques2, Renato W Veloso3
1Departamento de Solos, Universidade Federal de Viçosa, Avenida Peter Henry Rolfs S/N, Campus Universitário, Viçosa, MG, CEP 36570-900, Brazil.
Environmental geochemistry and health
|February 6, 2026
概括
石的应用使土壤在9年内以稀土元素 (REE), (U) 和 (Th) 丰富土壤. 虽然REE水平下降,但和积累,表明潜在的长期土壤污染风险.
科学领域:
- 环境化学环境化学
- 土壤科学 土壤科学
- 地质化学 地质化学
背景情况:
- 石是一种矿开采的副产品,被用作土壤调节剂,以改善土壤特性并减少的毒性.
- 石可以含有稀土元素 (REE), (U) 和 (Th) 等污染物,引发了对土壤和环境质量的长期担忧.
- 关于这些污染物的长期命运和在石膏应用后在土壤配置中传播的研究有限.
研究的目的:
- 为了研究长期 (9年) 的REE,U和Th的重新调动和分布,在石膏应用后,在经过极度气候变化的Oxisol中.
- 评估不同土壤深度污染物度和元素比率的时间变化.
- 了解土壤特征和合体成分对污染物的行为的影响.
主要方法:
- 在不同年份 (2005年至2013年) 的四个土壤块中应用石膏 (28公-1).
- 2014年从经过处理的地块和参考区域采集土壤样本.
- 土壤样本的酸性消化,然后进行诱导合等离子体质谱学 (ICP-MS) 分析以确定REE,U和Th的量化.
主要成果:
- 石膏应用引入了大量的REE (1681毫克-1千克),主要是轻型REE (LREE),进入土壤.
- 与基准面积相比,在40厘米以上的经过处理的土壤中观察到LREE,特别是 (Ce) 的时间丰富.
- 在9年内,REE度普遍下降,但 (Th) 和 (Sc) 显示积累,而 (U) 和 (Y) 显示出更高的流动性和损失.
结论:
- 石的应用导致土壤中潜在有毒元素 (REE,U,Th) 的分布发生时间和空间变化.
- 这些元素的长期行为受到土壤特性,背景水平和合石膏成分的影响.
- 调查结果强调,需要仔细评估石对环境的影响,因为特定污染物的积累和流动性.
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