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Updated: Feb 10, 2026

Estimation of Plant Biomass Lignin Content using Thioglycolic Acid TGA
Published on: July 24, 2021
三基改性素和相应的基于生物质的基胺树脂:合成和特性
Nien-Hsun Wu1, Yi-Ming Sun2, Ying-Ling Liu1
1Department of Chemical Engineering, National Tsing Hua University, No. 101, Sec. 2, Kuang-Fu Road, Hsinchu 300044, Taiwan.
环境友好,可回收的耐热树脂是使用素制成的. 添加一个素-基 (OL-TK) 修饰剂提高了基于二碳酸 (FDCA) 的树脂的机械性能和高温性能,而不妨碍可回收利用性.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 可持续化学 可持续化学
背景情况:
- 从生物质中开发可持续的聚合物材料至关重要.
- 可回收的固热树脂为传统的不可回收塑料提供了替代品.
- 易于获得的生物质成分素具有作为先进材料原料的潜力.
研究的目的:
- 为了合成和表征基于素的新型二基胺树脂.
- 为了研究氨酸-三氨酸 (OL-TK) 作为二碳酸 (FDCA) 基二氨酸树脂的反应性修饰剂的潜力.
- 评估OL-TK对改性树脂的机械性能,热性能和可回收性的影响.
主要方法:
- 从水溶性木质素合成木质素-三 (OL-TK).
- OL-TK与tris-(2-aminoethyl) -amine (TREN) 的交叉链接以形成以素为基础的树脂.
- 修改基于FDCA的二基胺树脂,使用不同的OL-TK%的重量.
- 机械性质的表征,玻璃过渡温度 (Tg),应力放松和可回收性.
主要成果:
- 基于素的二基胺树脂呈现出高Tg (165°C),但表现出脆性.
- 含有红素的FDCA基树脂表现出玻璃材料的特性,包括减压和可回收性.
- 添加3%的OL-TK增强了机械性能并抑制了高温爬行,而不影响热性能或可回收性.
- 较高的OL-TK含量 (7重 %) 改善了机械性能,但导致了素聚合,并对回收性能产生了负面影响.
结论:
- 素可以有效地用于制造具有可调节性质的可回收热固化树脂.
- OL-TK 作为 FDCA 基二基胺树脂的有益反应修饰剂,增强性能并保持最佳度的可回收性.
- 仔细控制OL-TK含量至关重要,以平衡改进的材料性能和有效的回收利用.
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