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Molecules with Multiple Chiral Centers02:25

Molecules with Multiple Chiral Centers

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Molecules that possess multiple chiral centers can afford a large number of stereoisomers. For instance, while some molecules like 2-butanol have one chiral center, defined as a tetrahedral carbon atom with four different substituents attached, several molecules like butane-2,3-diol have multiple chiral centers. A simple formula to predict the number of stereoisomers possible for a molecule with n chiral centers is 2n. However, there can be a lower number where some of the stereoisomers are...
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Chirality02:25

Chirality

29.7K
Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
29.7K
Chirality in Nature02:30

Chirality in Nature

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Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
17.3K
Molecules and Compounds02:38

Molecules and Compounds

69.2K
Atoms and Molecules
69.2K
Electron Transport Chains01:28

Electron Transport Chains

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The final stage of cellular respiration is oxidative phosphorylation that consists of two steps: the electron transport chain and chemiosmosis. The electron transport chain is a set of proteins found in the inner mitochondrial membrane in eukaryotic cells. Its primary function is to establish a proton gradient that can be used during chemiosmosis to produce ATP and generate electron carriers, such as NAD+ and FAD, that are used in glycolysis and the citric acid cycle.
The ETC is comprised of...
113.0K
Chirality at Nitrogen, Phosphorus, and Sulfur02:30

Chirality at Nitrogen, Phosphorus, and Sulfur

7.1K
Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
7.1K

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相关实验视频

Updated: Feb 11, 2026

Microcrystal Electron Diffraction of Small Molecules
09:48

Microcrystal Electron Diffraction of Small Molecules

Published on: March 15, 2021

7.2K

一个简单的方法是使用三原子分子来实现亚秒电子性翻转.

Dietrich Haase1, Jörn Manz1, Beate Paulus1

  • 1Institut für Chemie und Biochemie, Freie Universität Berlin, 14195 Berlin, Germany. jmanz@chemie.fu-berlin.de.

Physical chemistry chemical physics : PCCP
|February 10, 2026
PubMed
概括

在阿基拉分子中,电子性翻转可以通过弗兰克-康登激发来诱导. 这种量子动力学模拟集中在NSF分子上,证明了超快化学中的关键效应.

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A Micropatterning Assay for Measuring Cell Chirality
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A Micropatterning Assay for Measuring Cell Chirality

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A Manual Small Molecule Screen Approaching High-throughput Using Zebrafish Embryos
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A Manual Small Molecule Screen Approaching High-throughput Using Zebrafish Embryos

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相关实验视频

Last Updated: Feb 11, 2026

Microcrystal Electron Diffraction of Small Molecules
09:48

Microcrystal Electron Diffraction of Small Molecules

Published on: March 15, 2021

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A Micropatterning Assay for Measuring Cell Chirality
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A Micropatterning Assay for Measuring Cell Chirality

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A Manual Small Molecule Screen Approaching High-throughput Using Zebrafish Embryos
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科学领域:

  • 量子化学是一种量子化学.
  • 超快速光谱法 超快速光谱法
  • 分子物理分子物理学

背景情况:

  • 电子性翻转在无性分子中是一个重要的研究领域.
  • 了解这些现象对于attosecond和femtosecond化学和物理学的进步至关重要.

研究的目的:

  • 为了研究电子奇拉性翻转在无奇拉性分子中的诱导.
  • 探索弗兰克-康登激发在NSF分子中的这一过程中的作用.

主要方法:

  • 使用量子动力学模拟.
  • 使用弗兰克 - 康登激发.
  • 在NSF分子中研究电子状态的A' + A"叠加.

主要成果:

  • 证明了通过简单的弗兰克-康登激发可以诱导电子奇拉性翻转.
  • 在面向曲的三原子异核分子NSF中展示了这种效应.
  • 模拟了电子A'基本状态和第一个激发的A"状态的A' + A"叠加.

结论:

  • 弗兰克-康登激发是一种有效的方法来诱导电子性翻转.
  • NSF分子作为观察这种量子现象的模型系统.
  • 这些发现有助于理解分子中的超快电子动态.