剪切和表面活性剂辅助分解和恢复的粒子稳定油水接口
Malek El-Aooiti1, Dérick Rousseau1
1Department of Chemistry and Biology, Toronto Metropolitan University, Toronto, Ontario M5B 2K3, Canada.
Langmuir : the ACS journal of surfaces and colloids
|February 11, 2026
概括
这项研究表明,颗粒稳定乳液可以在剪切后恢复其结构. 然而,破坏结构的表面活性剂会永久削弱表面膜,影响乳液稳定性和分解性质.
科学领域:
- 合体和表面科学科学
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
背景情况:
- 颗粒稳定乳液在食品和石化工业中至关重要.
- 这些乳液的稳定性在很大程度上取决于界面上的粒子层.
- 了解界面类风湿学是控制乳液分解的关键.
研究的目的:
- 为了研究切割下的颗粒膜的再生分解和回收.
- 为了确定破坏结构的表面活性剂对界面特性的影响.
- 为了将界面变化与乳液稳定性相关联.
主要方法:
- 在平面油水界面薄膜上的实验,使用糖单酸盐 (GMS) 晶体.
- 应用不同的剪切条件来评估薄膜反应.
- 添加索比坦单酸盐 (SMO) 表面活性剂以评估其作用.
主要成果:
- 介面膜显示了基于应变的弹性和粘性状态之间的可逆转变.
- 比单酸盐 (SMO) 永久性地降低了界面弹性模量 (G) 和张力.
- 剪切削弱的薄膜导致粘弹性质的不可逆转的损失.
结论:
- 颗粒稳定接口可以在剪切后恢复G',但表面活性剂可能会导致不可逆转的变化.
- 破坏结构的表面活性剂通过改变界面粘性弹性来破坏乳液的稳定性.
- 这些发现有助于设计具有可调节分解特性的乳液.
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