合成双子-曼尼克基高效腐蚀抑制剂用于油田酸化
Yi Luo1,2, Zhongying Xu1,3, Yu Chen4
1College of Petroleum Engineering, Xi'an Shiyou University, Xi'an, Shaanxi, 710065, China. tangying78@xsyu.dedu.cn.
Physical chemistry chemical physics : PCCP
|February 11, 2026
概括
一种新的Gemini-Mannich基腐蚀抑制剂 (BPFC) 提供了对酸腐蚀的优越保护. 这种有效的抑制剂通过金属表面的分子吸附来提高腐蚀效率.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 腐蚀科学 腐蚀科学
背景情况:
- 功能组的结合是改善腐蚀抑制的关键策略.
- 开发高度溶解和高效的腐蚀抑制剂对于工业应用至关重要.
研究的目的:
- 为了合成和表征一种新的双子-曼尼克基腐蚀抑制剂 (BPFC).
- 为了评估BPFC在5%HCl中的腐蚀抑制性能.
- 为了阐明腐蚀抑制的机制.
主要方法:
- 使用 piperazine,cyclohexanone 和 formaldehyde 合成 BPFC 的一个步骤.
- 在不同温度和度下进行电化学腐蚀试验 (电动极化,EIS).
- 表面分析技术和量子化学计算 (DFT) 和分子动力学模拟.
主要成果:
- 在5% HCl 中,BPFC 在353 K 和2.11 × 10−2 M 时表现出极好的防腐效率 (92.66%) .
- BPFC作为混合类型的抑制剂,抑制阳极和阴极反应.
- 吸附遵循兰格穆尔等热法,表明主要是物理吸附.
结论:
- BPFC是一种高效,稳定的腐蚀抑制剂,具有卓越的溶解性.
- 抑制作用归因于BPFC分子通过三级氨基和C=O群的吸附,形成一个保护层.
- 量子化学计算支持吸附机制和功能组在抑制腐蚀中的作用.
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