在聚烯介电薄膜中的高温稳定性和能量储存性能的协同增强通过分子陷工程
Cheng Yao1,2, Dong Ma3, Jingchun Hou3
1State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049, China.
Materials horizons
|February 11, 2026
概括
研究人员使用分子陷工程增强了聚烯 (PP) 介电薄膜. 这一策略改善了先进的功率电子和薄膜电容器的能量存储和热稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 电气工程 电气工程
背景情况:
- 基于聚烯 (PP) 的介电薄膜在储能密度和热稳定性方面具有局限性.
- 这些局限性阻碍了它们在高温功率电子设备中的使用.
研究的目的:
- 提高PP薄膜的介电性能,热可靠性和可加工性.
- 为PP开发一个分子陷工程战略.
- 为了实现高级应用的基于PP的高性能介电薄膜.
主要方法:
- 在PP矩阵中通过化混合将4 - - 基-2-基基 (AOHBP) 纳入.
- 形成深层电荷陷以抑制载体迁移和泄漏电流.
- 诱导链接效应以提高矩阵刚性和热稳定性.
主要成果:
- 优化的PP/AOHBP-2膜实现了802 MV m-1的分解强度.
- 超高放电能量密度在25°C时为9.16 J cm-3和在120°C时为5.33 J cm-3.
- 保持高储能效率 (>90%在25°C,88.3%在120°C) 提高了循环稳定性和自我修复能力.
结论:
- 分子陷工程是高性能PP介电膜的可扩展策略.
- 经过AOHBP修改的PP提供了卓越的储能能力和耐热性.
- 这种方法适用于下一代薄膜电容器在苛刻的应用中.
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