在无流式Zn-Br电池中为超高容量的逐步激活引导的Zn沉积
Jaewoong Han1,2, Mingyu Lee1,3, Hyuntae Lee4
1Department of Energy Science & Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu, Republic of Korea.
Small (Weinheim an der Bergstrasse, Germany)
|February 11, 2026
概括
无流式Zn-电池通过使用一种新的阶段激活 (SWA) 电极实现超高容量. 这种设计防止了树岩的形成,并使稳定的循环实现了实际的能量储存.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 无流电池 (FL-ZBB) 与传统流电池相比具有优势,但在利用和面积容量方面面临挑战.
- 在FL-ZBB中的电极经常表现出顶层涂层和树积累,阻碍可逆涂层/脱落和整体性能.
研究的目的:
- 开发FL-ZBB的新型电极架构,使沉积均,并提高实际可行性.
- 克服利用的局限性,并实现FL-ZBB的超高面积容量.
主要方法:
- 引入一个逐步激活 (SWA) 电极架构.
- 设计涉及隔热多孔膜,将堆叠的碳纤维 (CF) 层分开,并控制的透率.
- 在高电流循环下对FL-ZBB的SWA电极性能进行评估.
主要成果:
- 该SWA电极引导无顶,自下至上顺序沉积.
- 带有SWA电极的FL-ZBB在20 mA cm-2.2的10000个周期中表现出稳定的高库伦比和能量效率.
- 在FL-ZBB中实现了100 mAh cm-2的稳定循环,最大限度地将ZnBr2的利用率提高到~33%.
结论:
- SWA电极设计有效地解决了FL-ZBB中的涂问题.
- 这种简单可扩展的方法使高容量运行和在无流电池和其他金属沉积有限系统中广泛适用.
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