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Updated: Feb 13, 2026

Enzymatic Synthesis of Epoxidized Metabolites of Docosahexaenoic, Eicosapentaenoic, and Arachidonic Acids
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Published on: June 28, 2019

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Cu交换的基酸诱导了溶剂作用,以增强与H2O2的烯环氧化

Xiaojing Song1, Shuang Liu1, Jing Wang2

  • 1School of Chemical and Environmental Engineering, Liaoning University of Technology, Jinzhou, 121001, China. 1227519466@qq.com.

Dalton transactions (Cambridge, England : 2003)
|February 12, 2026
PubMed
概括

在多孔有机聚合物 (CuPMA/POPs) 上用铜替代的基酸增强了烯环氧化. 这种利用过氧化的催化剂显示出改进的转化和选择性,由协同的Cu替代和溶剂效应驱动.

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Acid-Catalyzed Ring-Opening of Epoxides

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Solvents

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In a dehydration reaction, a hydroxyl group in an alcohol is eliminated along with the hydrogen from an adjacent carbon. Here, the products are an alkene and a molecule of water. Dehydration of alcohols is generally achieved by heating in the presence of an acid catalyst. While the dehydration of primary alcohols requires high temperatures and acid concentrations, secondary and tertiary alcohols can lose a water molecule under relatively mild conditions.
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Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of peroxy acids to...
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