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由多功能添加剂诱导的协同结晶和缺陷被动化,用于>20%高效的基于碳的矿太阳能电池

Reza Ghayoor^1,2, Fatemeh Ghasemi¹, Fariba Tajabadi³

¹Center for Nanoscience and Nanotechnology, Institute for Convergence Science & Technology, Sharif University of Technology, Tehran 1458889694, Iran.

ACS applied materials & interfaces

|February 12, 2026

概括

这项研究介绍了2-烯-2-甲基硫酸 (AMPS) 作为碳基矿太阳能电池 (C-PSC) 的多功能添加剂. 通过被动化缺陷和减少离子迁移,AMPS提高了设备的效率,稳定性和结晶性.

科学领域:

材料科学材料科学材料科学
可再生能源可再生能源是可再生能源.
太阳能光伏发电是如何实现的

背景情况:

矿太阳能电池 (PSC) 显示出巨大的潜力,但存在稳定性和效率问题.
多功能分子添加剂是克服PSC这些局限性的关键.

研究的目的:

调查2-烯-2-甲基硫酸 (AMPS) 作为碳基PSC (C-PSC) 的添加剂.
评估AMPS增强结晶,消极缺陷和抑制离子迁移的能力.

主要方法:

密度函数理论 (DFT) 计算和光谱分析被用来研究AMPS-矿相互作用.
用不同的AMPS度制造和表征C-PSC.

主要成果:

AMPS表现出强大的界面结合,优选的Pb-SO3H协调,以及有效的缺陷被动化.
优化的AMPS内容导致了20.2%的冠军功率转换效率 (PCE),改善了填充因子和增强的电荷提取.
设备显示离子迁移减少,理想性系数较低,在经过1000小时的运行后保留了95%的初始PCE.

结论:

AMPS是一种具有成本效益的,可溶液加工的添加剂,可提高C-PSC的性能和稳定性.
通过调节结晶,使缺陷被动化,并抑制离子迁移,AMPS有效地稳定矿晶格.
这项工作提出了一个可扩展的战略,用于开发高效和稳定的下一代矿光伏.

关键词:

2-烯-2-甲基硫酸 (AMPS) 是一种基于碳的矿石太阳能电池结晶化结晶化的过程.缺陷被动化缺陷被动化墨水添加剂墨水添加剂多功能组是一个多功能组.

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