钻石的光谱极限为520 GPa和预计的带隙关闭
A Hilberer1,2, P Loubeyre3,4, C Pépin5,6
1CEA DAM DIF, Arpajon, France. antoine.hilberer@cea.fr.
Nature communications
|February 12, 2026
概括
在极端压力 (高达520 GPa) 下,钻石子失去透明度. 这项研究揭示了带隙缩小和预计的金属化,定义了超高压研究中钻石子细胞的操作限制.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 地质物理学 地质物理学
背景情况:
- 钻石是静态超高压实验中的关键光学窗口,可以在特拉帕斯卡状态下实现压力.
- 它们在多倍加巴压力下的光学性质变化仍然不太清楚,限制了实验能力.
研究的目的:
- 为了研究在极端压力下钻石的宽带光学属性变化.
- 量化分析吸收光谱,推断杆内部的应力概况.
- 确定用于超高压研究的钻石天细胞的运行极限.
主要方法:
- 从紫外线到红外线的宽带吸收测量波长高达520GPa.
- 钻石拉曼散射以确定沿轴和样品接口的应力概况.
- 使用推断的压力概况进行吸收光谱的定量分析.
主要成果:
- 随着压力增加,钻石的透明度明显下降.
- 检测到一个间接的带隙向红外线收窄,预计金属化接近560GPa.
- 在不同的形几何体中发现了通用光学行为,支持精致的拉曼边缘压力尺度.
结论:
- 这项研究定义了在极端压力下钻石天细胞的光谱运行极限.
- 这些发现对解释超高压实验的结果有重大影响,包括对金属化的说法.
- 了解光学变化对于推进凝聚物质物理学和地球物理学研究至关重要.
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