基于聚乙烯的相变材料被六边形化纳米颗粒修改,具有增强的热稳定性和热导电性
Beata Macherzyńska1, Adrianna Pitera1, Katarzyna Nowicka-Dunal1
1Department of Glass Technology and Amorphous Coatings, Faculty of Materials Science and Ceramics, AGH University of Krakow, Al. Mickiewicza 30, 30-059 Krakow, Poland.
用六角化修改的聚乙烯显示出更好的导热性和稳定性,用于储能. 这种增强扩大了相变范围,减少了超冷却,优化了它们作为相变材料的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 聚乙烯 (PEW) 是合适的中温相变材料 (PCM).
- PEW的低导热率限制了它们的效率.
- 六角化 (h-BN) 具有高的导热性和稳定性.
研究的目的:
- 为了提高PEW的热性能,使用h-BN.
- 调查h-BN对PEW相位过渡行为和热稳定性的影响.
- 探索PEW/h-BN复合材料在储能方面的潜力.
主要方法:
- 修改PEW的h-BN (0.0250.5%) 的不同重量%.
- 差分扫描热量计 (DSC) 用于分析相位过渡.
- 热重力测量分析 (TGA) 用于评估热稳定性.
- 福利埃转换红外光谱 (FTIR) 用于化学结构分析.
主要成果:
- h-BN的添加改变了相位过渡,扩大了温度范围,并将超冷却从11°C降低到9°C.
- 热稳定性得到改善;5%的质量损失温度增加了~50°C.
- 导热率从0.30增加到0.40mW/K,而没有改变化学结构.
结论:
- 加入h-BN可以提高PEW的导热性和稳定性.
- PEW/h-BN复合材料为储能应用提供可调节的性能.
- 经过修改的PEW显示了作为相变材料的性能提高.
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