聚碳酸乙烯研磨辅助剂分子结构对水泥研磨效率和粉末流动性的影响
Yahya Kaya1, Veysel Kobya1, Yunus Kaya2
1Department of Civil Engineering, Faculty of Engineering, Bursa Uludag University, Bursa 16059, Turkey.
Polymers
|February 13, 2026
概括
这项研究探讨了分子结构如何影响在水泥生产中的聚碳酸 (PCE) 基研磨辅助剂 (GA). 具有平衡链条长度和比例的PCE5添加剂在研磨效率和粉末流动性方面显示出最佳的整体性能.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 建筑材料 建筑材料
背景情况:
- 基于聚碳酸 (PCE) 的研磨辅助剂 (GA) 对于水泥生产至关重要.
- 关于PCE分子结构对研磨效率和水泥性能的综合影响的研究有限.
研究的目的:
- 研究PCE分子结构参数对研磨效率,水泥性能和粉末流动性的影响.
- 合成和评估七种不同的基于PCE的GA,具有不同的分子结构.
主要方法:
- 通过改变主链长度,侧链长度和侧链/主链比率,合成了七个基于 PCE 的 GAs.
- 使用富里埃变换红外光谱学 (FTIR) 和凝透色谱学 (GPC) 进行了添加剂的特征.
- 在不同的GA剂量下评估了水泥的研磨效率,颗粒大小分布 (PSD) 和粉末流动性.
主要成果:
- 增加GA剂量通常会提高研磨效率并缩小PSD.
- 较长的主链长度提高了研磨性能;中长主链长度提高了粉末的流动性.
- 由于其特定的分子结构,PCE5添加剂表现出最平衡和最高的整体性能.
结论:
- 分子结构显著影响基于PCE的GA在水泥研磨中的性能.
- 优化主链长度和侧链/主链比率是提高研磨效率和粉末流动性的关键.
- PCE5添加剂代表了为平衡性能的优化配方.
相关概念视频
Hydration of Cement
974
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
974
Soundness of Cement
588
The soundness of cement refers to the ability of cement paste to retain its volume after setting. Unsound cement can lead to expansion and structural damage due to the presence of free lime, magnesia, and calcium sulfate. Free lime hydrates very slowly, expanding and causing unsoundness, which is difficult to detect because it intercrystallizes with other compounds. Magnesia also reacts with water, forming crystals that can disrupt the cement's structure. Calcium sulfate can create...
588
Ethers from Alcohols: Alcohol Dehydration and Williamson Ether Synthesis
13.0K
Overview
Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
Preparation of Ethers by Alcohol Dehydration
In this method, in the presence of protic acids, alcohol dehydrates to produce alkenes and ethers under different conditions. For example, in the presence of sulphuric acid, dehydration of ethanol at 413 K yields ethoxyethane, whereas it yields ethene at 443 K.
Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
Preparation of Ethers by Alcohol Dehydration
In this method, in the presence of protic acids, alcohol dehydrates to produce alkenes and ethers under different conditions. For example, in the presence of sulphuric acid, dehydration of ethanol at 413 K yields ethoxyethane, whereas it yields ethene at 443 K.
13.0K
Crown Ethers
6.1K
Crown ethers are cyclic polyethers that contain multiple oxygen atoms, usually arranged in a regular pattern. The first crown ether was synthesized by Charles Pederson while working at DuPont in 1967. For this work, Pedersen was co-awarded the 1987 Nobel Prize in Chemistry. Crown ethers are named using the formula x-crown-y, where x is the total number of atoms in the ring and y is the number of ether oxygen atoms. The term 'crown' refers to the crown-like shape that these ether molecules...
6.1K
Structure and Nomenclature of Ethers
14.9K
Structure and Bonding
Ethers are organic compounds with an ether functional group which is characterized by an oxygen atom connected to two — identical or different — alkyl, aryl, or vinyl groups. The C–O–C linkage in dimethyl ether — the simplest ether — has an approximately tetrahedral bond angle of 110.3 degrees. The oxygen atom is sp3- hybridized, with the C–O distance being about 140 pm.
Classification of Ethers
Based on their attached substituent...
Ethers are organic compounds with an ether functional group which is characterized by an oxygen atom connected to two — identical or different — alkyl, aryl, or vinyl groups. The C–O–C linkage in dimethyl ether — the simplest ether — has an approximately tetrahedral bond angle of 110.3 degrees. The oxygen atom is sp3- hybridized, with the C–O distance being about 140 pm.
Classification of Ethers
Based on their attached substituent...
14.9K
Molecular Models
43.9K
Physical models representing molecular architectures of chemical compounds play essential roles in understanding chemistry. The use of molecular models makes it easier to visualize the structures and shapes of atoms and molecules.
43.9K


