化聚烯胺水溶液的粘度特征
Mamdouh T Ghannam1, Mohamed Y E Selim2, Ahmed Thaher2
1Department of Chemical and Petroleum Engineering, College of Engineering, United Arab Emirates University, Al-Ain P.O. Box 15551, United Arab Emirates.
这项研究表明,化聚烯胺 (CPAA) 溶液在200s-1以下表现出剪切稀释行为,以更高的速度过渡到剪切加厚. 粘度随着CPAA度的增加而增加,但随着温度和电解质的存在而下降.
科学领域:
- 聚合物科学 聚合物科学
- 类风病学 类风病学 类风病学
- 材料科学 材料科学 材料科学
背景情况:
- 酸聚烯胺 (CPAA) 广泛应用于工业应用中,需要进行流体修饰.
- 了解CPAA溶液类风湿学对于在各种条件下优化性能至关重要.
- 高盐度和高温度环境对聚合物溶液的稳定性和流动行为构成重大挑战.
研究的目的:
- 为了研究CPAA溶液的风湿性质.
- 评估CPAA度,剪切率,温度和电解质 (NaCl,CaCl2) 对粘度和流量性能的影响.
- 为了确定从剪切稀释到剪切加厚行为过渡的临界剪切速率.
主要方法:
- 使用安东尼·帕尔旋转风力计进行流动行为分析.
- 在500-5000 ppm的度范围内测试了CPAA溶液.
- 研究温度在20°C间隔的20-80°C之间,电解质度为0-10Wt%的NaCl和CaCl2.
主要成果:
- CPAA解决方案在200s-1以下表现出非牛顿式剪切稀释行为,在此速率以上过渡到剪切加厚.
- 随着CPAA度的增加,动态粘度显著增加 (例如,在10秒-1时500-5000ppm的2.4到33.8mPa·s).
- 粘度随着温度的增加而显著下降 (例如,在20至80°C的10s−1时,在5000ppm时33.8至18.3mPa·s),并且由于NaCl和CaCl2的存在而减少.
结论:
- CPAA 溶液表现出复杂的,对度,剪切速率,温度和电解质敏感的风湿性行为.
- 识别的剪速过渡对于预测工业环境中的流量性能至关重要.
- 结果为优化CPAA配方在具有挑战性的高盐度和高温应用中提供了宝贵的见解.
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