对修改的P-V-T模型进行实验研究,以改善注射成型半晶聚合物的收缩预测
Shia-Chung Chen1,2, Yan-Xiang Liang3, Chi-Je Ding3
1R&D Center for Smart Manufacturing, Chung Yuan Christian University, Taoyuan 32023, Taiwan.
Polymers
|February 13, 2026
概括
一种新的热变换方法 (TETM) 通过识别内腔固化,准确地预测聚烯 (PP) 收缩. 该方法通过提供可靠的过程相关数据,提高了注塑成型的尺寸精度.
科学领域:
- 聚合物科学与工程 聚合物科学与工程
- 材料科学 材料科学 材料科学
- 制造过程 制造过程 制造过程
背景情况:
- 像聚烯 (PP) 这样的半晶体聚合物的注射成型面临着由于冷却和结晶过程中的体积变化而导致部分收缩的挑战.
- 精确预测收缩对于尺寸准确性至关重要,但标准材料测试往往无法捕捉内腔条件 (冷却速率,压力历史).
- 现有的P-V-T (压力-体积-温度) 模型与不一致的固化温度数据作斗争,从而损害了收缩预测的可靠性.
研究的目的:
- 开发一种使用泰特方程修改的P-V-T框架,以改善PP注塑中的收缩预测.
- 引入和验证热热转换方法 (TETM) 来直接从内腔测量中确定与过程相关的固化参数.
- 为了提高P-V-T数据的实际可用性,以控制不同成型条件下的收缩行为.
主要方法:
- 开发了一个修改后的P-V-T框架,包括泰特方程和新的热热转换方法 (TETM).
- 使用一个红外传感器监测洞内融温度,以捕获结晶诱导的热释放.
- 从TETM检测到的温度-时间平原中确定了有效的固化点和结晶-完成温度 (目标特定体积).
- 执行了不同目标特定体积,化温度和模具温度的实验,采用了两阶段包装策略.
主要成果:
- TETM成功地确定了与过程相关的固化时间和结晶完成温度,克服了标准材料测试的局限性.
- 与传统方法相比,通过TETM确定的特定目标体积显示出与测量收缩率的更一致和近线性关系.
- 经过修改的P-V-T框架在固化时间识别方面表现出更好的稳定性和用于收缩控制的实际可用性.
- 实验结果验证了TETM在增强在动态成型条件下的收缩预测可靠性的有效性.
结论:
- 热热转换方法 (TETM) 提供了一种可靠的方法,用于确定PP注塑中关键的固化参数.
- 开发的P-V-T框架通过利用洞内数据显著提高了收缩预测的准确性和一致性.
- 这项研究增强了P-V-T信息的实际应用,以实现注塑聚合物零件的精确尺寸控制.
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