在中依赖温度的氧气耗尽:对β到α相变的定量分析
Sonali Patajoshi1, P N Rao2, Sammar Tayyab3
1Department of Physics, Shiv Nadar Institution of Eminence, School Of Natural Sciences, Dadri, Gautam Buddha Nagar, UTTAR PRADESH, 201314, India.
Journal of physics. Condensed matter : an Institute of Physics journal
|February 13, 2026
概括
在200°C以上的温度下,β- (β-W) 薄膜因氧气脱吸而转化为α-W (α-alpha) 阶段. 这种热行为对于理解β-WW至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术 纳米技术
背景情况:
- 乙- (β-W) 薄膜对于自旋式和磁性随机访问存储器应用至关重要.
- 对于β-W薄膜的热稳定性和相位转换行为,人们对它们的理解尚不充分,这阻碍了它们的技术应用.
研究的目的:
- 系统地研究β-W薄膜的热稳定性和相变.
- 阐明氧含量在β-W薄膜相变中的作用.
主要方法:
- 用于结构分析的X射线衍射 (XRD).
- 对表面组成和电子结构进行X射线光电子光谱 (XPS).
- 二次离子质谱 (SIMS) 和热溶解谱 (TDS) 用于组成深度分析和气体演变.
主要成果:
- 在加热超过200°C时,β-W膜不可逆转地转化为α-W相.
- 最初的β-W膜含有大约12%的氧气,在500°C的化后,氧气减少到几个百分点.
- 密度函数理论 (DFT) 和分子动力学模拟证实,在低氧度 (~10at.%) 的情况下,α相更稳定.
结论:
- 在热处理过程中,氧气脱吸驱动了从β-W到α-W的相变.
- 了解这种热行为对于优化自旋电子设备中的β-W膜至关重要.
- 这些发现为先进的内存应用提供了对材料性能的关键见解.
相关概念视频
Phase Transitions
23.3K
Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
23.3K
Phase Transitions: Sublimation and Deposition
20.4K
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
20.4K
Phase Transitions: Melting and Freezing
15.3K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
15.3K
Phase Transitions: Vaporization and Condensation
21.6K
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules...
21.6K
Temperature Dependence on Reaction Rate
89.3K
The Collision Theory
Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. This premise is the basis for a theory that explains many observations regarding chemical kinetics, including factors affecting reaction rates.
The collision theory is based on the postulates that (i) the reaction rate is proportional to the rate of reactant collisions, (ii) the reacting species collide in an orientation allowing contact between...
Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. This premise is the basis for a theory that explains many observations regarding chemical kinetics, including factors affecting reaction rates.
The collision theory is based on the postulates that (i) the reaction rate is proportional to the rate of reactant collisions, (ii) the reacting species collide in an orientation allowing contact between...
89.3K
Temperature Dependent Deformation
417
In a nonhomogeneous rod made up of steel and brass, restrained at both ends and subjected to a temperature change, several steps are involved in calculating the stress and compressive load. Due to the problem's static indeterminacy, one end support is disconnected, allowing the rod to experience the temperature change freely. Next, an unknown force is applied at the free end, triggering deformations in the rod's steel and brass portions. These deformations are then calculated and added...
417


