高能量的半经典多态动力学O + O2碰撞:电子刺激对能量放松的影响

Xiaorui Zhao1,2, Yinan Shu3, Donald G Truhlar3

  • 1Center for Combustion Energy, Tsinghua University, Beijing 100084, P. R. China.

概括

电子激发对O+O2碰撞中的振动能量转移产生影响. 一个新的模型解释了这一点,显示非adiabatic效应在高温流中增加了20%的能量放松时间.

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