通过持久的化学稳定微型氧化物.
Kai Zhang1,2, Huan Pang1,3, Zaichun Liu1
1Department of Applied Chemistry, School of Chemistry and Materials Science, Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, China.
Angewandte Chemie (International ed. in English)
|February 15, 2026
概括
微型氧化 (μSiOx) 阳极对高能电池具有前景. 化学稳定固体电解质间相 (SEI),增强阳极稳定性和性能,用于实际应用.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 微型氧化 (μSiOx) 由于其低成本和高容量,是高能电池的有前途的阳极材料.
- 在μSiOx阳极上固体电解质间相 (SEI) 的不稳定性导致不可逆转的消耗和电解质分解,阻碍了长期稳定性.
研究的目的:
- 在微型氧化 (μSiOx) 阳极上增强固体电解质间相 (SEI) 的稳定性.
- 为了提高电池的μSiOx阳极的长期循环性能和容量保留.
主要方法:
- 利用化学的双重功能来调节接口和保护大气.
- 采用高度可逆的演变和氧化还氧化反应来稳定阳极表面.
主要成果:
- 在1°C下达到1568 mAh g−1的放电容量,充电容量为1600 mAh g−1.
- 在700mAhg-1.1的充电容量下,经过2000小时的稳定循环,具有~98%的库伦比效率.
- 在600小时循环后,在3 mAh的高面积容量下,在2.93 mAh cm-2下维持了~2.93 mAh cm-2的放电容量.
结论:
- 基于化学的策略有效地提高了在μSiOx阳极上的SEI稳定性.
- 这种方法为稳定高容量的μSiOx阳极提供了可行的解决方案,促进了它们在电池中的实际应用.
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