通过相分离工艺从煤炭飞灰中去除金属和生产高粉
An Jiang1, Jingwen Wu2, Boyu Qu2
1School of Building Intelligence, Jiangsu Vocational Institute of Architectural Technology, Xuzhou 221100, P. R. China.
Waste management (New York, N.Y.)
|February 15, 2026
概括
这项研究提出了一种新的热相分离-酸方法,用于从煤炭飞灰 (CFA) 中净化. 该过程有效地去除金属氧化物,产生高纯度的,用于有价值的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 由于经济增长和城市化,煤炭飞灰 (CFA) 的产量正在增加.
- 在CFA利用方面取得的有限进展构成了废物管理的挑战.
- 碳酸是用于高价值应用的丰富的二氧化 (SiO2) 来源.
研究的目的:
- 开发一种有效的方法来从CFA中回收和净化二氧化.
- 为了优化金属氧化物去除的热相分离和酸化参数.
- 调查过程中相位分离和金属迁移的机制.
主要方法:
- 使用热相分离-酸技术,使用B2O3作为相分离剂.
- 系统地调查最佳过程参数,包括B2O3的添加,温度和保持时间.
- 采用分子动力学 (MD) 模拟来理解原子尺度机制.
主要成果:
- 在最佳条件下达到超过95%的金属氧化物去除效率 (25重量%B2O3,1100°C,1小时).
- 制造了一种高酸盐产品,纯度为97.22%.
- MD模拟证实了冷却过程中的快速相位分离.
结论:
- 开发的方法为CFA的资源利用提供了一种新且有效的方法.
- 高纯度的二氧化可以从CFA中回收,从而实现有价值的应用.
- 了解相位分离机制对于过程优化至关重要.
更多相关视频
08:00Author Spotlight: Standardizing the Development of Amine-Based Silica Composites as CO2 Adsorbents for Direct Air Capture
Published on: September 29, 2023
3.3K
10:45Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition
Published on: February 5, 2022
4.6K
相关概念视频
Steel Manufacturing
1.5K
Steel manufacturing is a multi-stage process that begins by smelting iron ore into cast iron in a blast furnace. This initial stage involves layering iron ore with coke, a type of fuel, and crushed limestone within the furnace. The coke is ignited with a high volume of air, leading to the creation of carbon monoxide, which acts to reduce the iron ore to pure iron.
During this smelting process, limestone plays a crucial role by forming slag. Slag captures impurities within the molten iron, such...
During this smelting process, limestone plays a crucial role by forming slag. Slag captures impurities within the molten iron, such...
1.5K
Sample Preparation for Analysis: Advanced Techniques
1.5K
Accurate analysis of complex samples often requires advanced preparation techniques to achieve reliable and reproducible results. Samples containing inorganic or organic materials can be challenging to dissolve or decompose effectively. Standard sample preparation methods include acid digestion, fusion, dry ashing, and wet digestion.
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
1.5K
Washing, Drying, and Ignition of Precipitates
6.8K
After filtration, the precipitate is washed to remove coprecipitated impurities and any remaining mother liquor. Colloidal precipitates, such as silver chloride, are washed with an electrolyte (such as dilute nitric acid) to prevent the peptization of the precipitate. In the case of slightly soluble precipitates, the wash solution contains a common ion to reduce solubility. Lead sulfate, which is slightly soluble in water, is washed with dilute sulfuric acid. Similarly, wash solutions may be...
6.8K
Precipitation and Co-precipitation
4.4K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
4.4K
Coagulation
1.5K
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
1.5K
Filtration
5.3K
Filtration is a physical separation process that involves passing a suspension through a porous medium to separate solids from fluids. During filtration, solids collect on the porous medium while liquids, also collectively known as the filtrate, pass through. The filtration medium is selected based on the filtration purpose, quantity, and nature of the precipitate. The general criteria for a suitable filtering medium are that it is inert, mechanically strong, nonabsorbent toward dissolved...
5.3K
