对比纳米结构CNF和其他纤维素形式的化为能源应用
Ana Carolina Marotti Dias1, Cesar Liberato Petzhold2, Leena Pitkänen3
1Seção de Engenharia Química, Instituto Militar de Engenharia, Praça General Tibúrcio 80, 22290-270 Rio de Janeiro, Brazil.
研究人员开发了纤维素纳米纤维 (CNF) 的化方法,发现真空过对于保存纳米结构至关重要. 这为各种纤维素来源的新酸纤维素材料开辟了可能性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 纳米技术纳米技术
背景情况:
- 传统的纤维素化通常使用线性纤维素 (LC).
- 纳米纤维素由于其纳米尺度的特性,提供了潜在的优势.
- 在加工过程中保持纳米结构对于新型应用至关重要.
研究的目的:
- 为纤维素纳米纤维素 (CNF) 开发化反应条件.
- 研究CNF的脱水方法,同时保持纳米特征.
- 为了比较化CNF与化林特纤维素 (LC) 和微晶纤维素 (MCC).
主要方法:
- 使用重力过,真空过,离心,烤箱干燥和冷干燥来脱水CNF.
- 脱水CNF的化和LC和MCC的比较化.
- 使用尺寸排除色谱,SEM,FTIR,XRD,TGA和元素分析进行表征.
主要成果:
- 涉及加热或冷的脱水方法导致不可逆转的纳米纤维聚合.
- 真空过是准备化CNF的唯一合适的脱水方法.
- 虽然替代度很低,但从CNF,LC和MCC中成功获得了化产品.
- 化CNF的结构和热性能与化LC和MCC相似.
结论:
- 真空过对于在不损害纳米结构的情况下为化准备CNF至关重要.
- 开发的合成方法可用于化不同来源和形态的纤维素.
- 需要进一步优化,以达到适合能源应用的替代程度.
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