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Updated: Feb 18, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Published on: July 19, 2019

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协同的质子电子转移最大限度地减少了对被吸收的酸电催化剂的替代效应

Vennela Mannava1, Logan E Smith2, Joel G Gardner1

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|February 16, 2026
PubMed
概括

分子修饰电极 (MME) 的合理设计具有挑战性. 这项研究表明,催化剂氧化还原潜力在MMEs中对于演化反应 (HER) 催化而言不如键能那么重要.

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Photochemical Electrocyclic Reactions: Stereochemistry

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The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
Selection Rules: Thermal Activation
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