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Updated: Feb 19, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Published on: April 9, 2018

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硫插入12组金属二硫酸盐复合物:金属依赖的平衡

Muhammad Sohail1, Carsten Heinsen1, Allen G Oliver1

  • 1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana, USA. etsui@nd.edu.

Dalton transactions (Cambridge, England : 2003)
|February 17, 2026
PubMed
概括

和的金属二硫酸盐复合物与变体具有结构上的差异. 硫插入反应揭示了复杂的产品混合物和不同的平衡常数,受金属性质的影响.

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Complexation reactions take place when dative or coordinate covalent bonds form between metal ions and ligands. The compounds formed in these reactions are called coordination compounds. The number of bonds formed between the metal ion and the ligands is called its coordination number. Generally, most metal ions in an aqueous solution are solvated by water molecules and thus exist as aqua complexes.
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