工程氧气空隙分布,以提高丰富的基氧化物阴极材料的结构稳定性
Dongye Liu1, Yin Zhao1, Linyao Dong1
1Institute of Science and Technology for New Energy, Xi'an Technological University, Xi'an 710021, China.
ACS applied materials & interfaces
|February 17, 2026
概括
在烧结过程中控制氧/比,稳定了富含的基氧化物 (LRMO). 这一策略增强了晶格氧气的稳定性,大大提高了电池性能和容量保留,用于下一代离子电池.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 富的基氧化物 (LRMO) 为先进的离子电池提供高特异性容量 (>250 mAh-1 g).
- 电池循环期间的氧气演变导致LRMO的结构不稳定性和容量衰减.
研究的目的:
- 提高LRMO的结构稳定性和电化学性能.
- 通过控制的烧结大气来减少散装氧气空缺含量,并提高网状氧气的稳定性.
主要方法:
- 使用不同的氧/ (O2/N2) 比率进行大气控制的烧结.
- 电化学循环测试,以评估容量保留和速率能力.
- 结构特征分析氧空位含量和晶格稳定性.
主要成果:
- O50样本 (50%O2/50%N2烧结) 在1°C (200mA g-1) 300个循环后保持了96.7%的容量.
- 观察到异常速率的能力,在5°C时为155.0mAhg-1和在10°C时为133.2mAhg-1.
- 该战略有效地减少了大量的氧气空缺,并增强了晶格氧气的稳定性.
结论:
- 大气控制烧结是一种简单但有效的设计高性能LRMO的方法.
- 这种方法同时提高了散装氧气的稳定性和表面氧气空缺的产生.
- 优化的LRMO显示出下一代高能离子电池的巨大潜力.
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