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Updated: Feb 20, 2026

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质子启动的可逆基 - 顶端挤出在宏多面基基纳博中

Jonathan Bould1, Miroslava Litecká1, William Clegg2

  • 1Institute of Inorganic Chemistry of the Czech Academy of Sciences, 250 68 Husinec-Řež č.p. 1001, Czech Republic.

Inorganic chemistry
|February 18, 2026
PubMed
概括

基纳博离子的质子化触发了根本性的重组,形成了新的中性物种. 脱还原会再生原来的离子,而进一步的反应会产生稳定的化合物或分解产物.

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
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