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Updated: Feb 20, 2026

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
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Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Published on: December 6, 2021

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在宏循环嵌入的单核中二次协调球效应 (bda) 水氧化催化剂

Gourab Das1, Daniel A P Friedewald1, Deqi Tang2

  • 1Institut für Organische Chemie & Center for Nanosystems Chemistry (CNC), Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.

Inorganic chemistry
|February 18, 2026
PubMed
概括

这项研究将催化剂与宏循环中的不同异环相结合,揭示了结构变化如何影响水氧化机制. 这些发现提供了对优化光催化水分裂用于清洁能源应用的见解.

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Regioselectivity and Stereochemistry of Hydroboration

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Hydroboration proceeds in a concerted fashion with the attack of borane on the π bond, giving a cyclic four-centered transition state. The –BH2 group is bonded to the less substituted carbon and –H to the more substituted carbon. The concerted nature requires the simultaneous addition of –H and –BH2 across the same face of the alkene giving syn stereochemistry.
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