氧化银纳米颗粒作为瓦特级离子交换膜燃料电池的固态氧化离子导体
Wonil Jung1, Jeehoon Shin1, Thomas E Mallouk1
1Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
概括
银氧化物纳米粒子在离子交换膜燃料电池 (AEMFC) 中充当氧化离子导体. 这使得无离子体阴极成为可能,为能量转换技术实现高功率密度和稳定的运行.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 能源转换 能源转换
背景情况:
- 无机固态氧化物离子导体对于高温性能量转换至关重要.
- 之前的研究表明有希望,但设备实施仍然有限.
研究的目的:
- 为了证明银-I) 氧化物 (Ag2O) 纳米颗粒作为阴离交换膜燃料电池 (AEMFC) 中的氧化离子导体.
- 为了研究使用Ag2O纳米粒子的无离子体阴极的性能.
主要方法:
- 用注射器过的1-6纳米的Ag2O纳米粒子被整合到Pt/C阴极中.
- 制造没有离子体的膜电极组件 (MEAs).
- 进行了电化学和结构分析.
主要成果:
- 集成Ag2O的MEA在2.4%的Ag2O负载下达到1.91W cm-2的峰值功率密度.
- 稳定的质量传输在100小时的连续运行中保持在0.6 A cm-2.
- 发现Ag2O负载会影响离子导电,孔隙结构和质量传输.
结论:
- 银氧化物纳米粒子可以在AEMFC中有效地作为氧化物离子导体发挥作用.
- 无机固态导体为高性能AEMFC阴极中的离子体提供了可行的替代方案.
- 这项研究为先进的无离子体能量转换装置铺平了道路.
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